The chemical compositions of defective regions in microcrystalline thin film Si solar cells are studied using energy-dispersive X-ray spectroscopy and electron energy-loss spectroscopy (EELS) in the scanning transmission electron microscope. Nanometer-reso ...
In this study visible light active iodine doped titanium dioxide samples prepared by sol-gel method were investigated. Photocatalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray fluorescence spectroscopy (XF ...
Energy research is to a large extent materials research, encompassing the physics and chemistry of materials, including their synthesis, processing toward components and design toward architectures, allowing for their functionality as energy devices, exten ...
We explore the local electronic signatures of molecular adsorption at coordinatively unsaturated binding sites in the metal-organic framework Mg-MOF-74 using X-ray spectroscopy and first-principles calculations. In situ measurements at the Mg K-edge reveal ...
Solid-state processes of introducing oxygen vacancies and transference of fluorine to n-TiO2 nanoparticles by co-milling with poly(tetrafluoroethylene) (PTFE) powder were examined by diffuse reflectance spectroscopy (DRS) of UV, visual, near- and mid-IR re ...
In this thesis we followed the synergetic approach of combining ultrafast optical and X-ray spectroscopies to unravel the electronic and geometric structural dynamics of the solvated binuclear transition metal complex [Pt2(P2O5H2)4] 4- (PtPOP). This molecu ...
The photocycle of rhenium carbonyl complexes, type facial-[Re(L)(CO)3(diimine)]n [L=halide / n=0, L=4-Ethyl-pyridine (Etpy)- Imidazole (ImH) /n=+1, diimine= bpy , 10- phenanthroline (phen), 4,4'-dimethyl-2,2'-bpy (dmb)] was studied using a set of ultrafast ...
The surface electronic and mol. structure of a new org. chromophore useful for dye-sensitized nanostructured solar cells was studied by electron spectroscopy. Initially the use of a simple mol. system contg. the polyene-diphenylaniline chromophore in a sol ...
2007
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The detection and quantification of small quantities of Cr in (La,Sr)MnO3/Y–ZrO2 solid oxide fuel cell (SOFC) cathodes by energy-dispersive X-ray spectroscopy (EDXS) is not straightforward as Cr X-ray emission lines overlap with La/Mn and O lines. This wor ...