Porosity in Aluminum Alloys : Visualization, Characterization, and Modeling

Porosity is one of the major defects in castings because it reduces the mechanical properties of a cast piece [1]. Porosity formation results from the effect of two concomitant mechanisms, namely solidification shrinkage and segregation/precipitation of gases [1]. A model for the prediction of microporosity, macroporosity and pipe shrinkage during the solidification of alloys has been developed at the Computational Materials Laboratory (LSMX-EPFL) [2]. This model has then been improved by taking into account the effect of various alloying elements and gases on porosity formation [3, 4, 5]. However, the modeling of two physical phenomena still needed to be improved: (i) the curvature influence and (ii) the hydrogen diffusion influence on the growth of pores. The effect of pinching, i.e. the pores are forced by the growing solid network to adopt a complex non spherical shape, induces curvature restriction to the pores. This pinching effect can be a limiting factor for the growth of pores and is too simply modeled in the model of Péquet et al. [2]. Several other pinching models exist, but a rigorous experimental study to validate either one of these models is needed. Additionally, Carlson et al. [6] have recently shown that hydrogen diffusion might also be a limiting factor for the growth of pores. In the model of Péquet et al. [2], this effect was not taken into account. This thesis is mainly aimed to (i) provide experimental results that specifically validate the pinching model developed by Couturier et al. [4], (ii) investigate the influence of hydrogen diffusion on the growth of pores and (iii) provide a new model that takes into account the pinching effect and the hydrogen diffusion influence on the growth of pores. At first, pores formed in aluminum-copper (Al-Cu) samples (cast under controlled conditions) have been analyzed using high resolution X-ray tomography. The influence of the alloy inoculant, copper content, cooling rate and initial hydrogen content on the morphology of pores has been investigated. The results show that the curvature of micropores pinched in either non-inoculated or inoculated Al-4.5wt%Cu alloys can be fairly well approximated to that of cylinders. The results also show that the pinching model must be function of (i) the volume fraction of the primary phase gα and (ii) the secondary dendrite arm spacing λ2. However, the influence of the initial hydrogen content appears to be negligible. The pinching model developed by Couturier et al. [4] accounts for these observations and their relation fits fairly well the average mean curvature value of our experimental data. A new model has been developed to calculate an effective hydrogen diffusion coefficient De(gs), that is a function of the volume fraction of solid only. For that purpose, in-situ X-ray tomography has been performed on Al-Cu alloys. For each volume fraction of solid 0.6 ≤ gs ≤ 0.9, a representative volume element of the microstructure has been obtained from th