This lecture discusses the behavior of carrier concentrations in extrinsic semiconductors, focusing on the influence of doping on the Fermi energy level. It begins by explaining the basic principles of carrier concentration, highlighting the distinction between intrinsic and extrinsic semiconductors. The instructor elaborates on the neutrality condition, which requires considering both free charges and fixed charges from ionized donors and acceptors. Various graphical representations illustrate how the Fermi energy level shifts with different doping levels and temperatures. The lecture also covers the Boltzmann approximation and complete ionization, providing mathematical expressions for carrier concentrations. The impact of temperature on carrier behavior is analyzed, showing how increased temperatures can lead to intrinsic-like behavior in heavily doped semiconductors. The concept of compensation effects when combining different dopants is introduced, emphasizing the resultant effective doping concentration. The lecture concludes with simplified methods for calculating carrier concentrations, demonstrating the practical applications of these principles in semiconductor physics.