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We demonstrate the use of the derivative voltammogram method to predict the selectivity of the photo-driven oxidation of 5-hydroxymethylfurfural (HMF) on a WO3 photoanode as a function of applied potential using only information obtained from the linear sweep voltammogram (LSV). This method can be a simple tool to gain an insight into reaction selectivity in photoelectrochemical cells.
Sophia Haussener, Isaac Thomas Holmes-Gentle, Franky Esteban Bedoya Lora, Roberto Valenza