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Concept
Fresco
Summary
Fresco (plural frescos or frescoes) is a technique of mural painting executed upon freshly laid ("wet") lime plaster. Water is used as the vehicle for the dry-powder pigment to merge with the plaster, and with the setting of the plaster, the painting becomes an integral part of the wall. The word fresco (affresco) is derived from the Italian adjective fresco meaning "fresh", and may thus be contrasted with fresco-secco or secco mural painting techniques, which are applied to dried plaster, to supplement painting in fresco. The fresco technique has been employed since antiquity and is closely associated with Italian Renaissance painting.
The word fresco is commonly and inaccurately used in English to refer to any wall painting regardless of the plaster technology or binding medium. This, in part, contributes to a misconception that the most geographically and temporally common wall painting technology was the painting into wet lime plaster. Even in apparently Buon fresco technology, the use of supplementary organic materials was widespread, if underrecognized.
Buon fresco pigment is mixed with room temperature water and is used on a thin layer of wet, fresh plaster, called the intonaco (after the Italian word for plaster). Because of the chemical makeup of the plaster, a binder is not required, as the pigment mixed solely with the water will sink into the intonaco, which itself becomes the medium holding the pigment. The pigment is absorbed by the wet plaster; after a number of hours, the plaster dries in reaction to air: it is this chemical reaction which fixes the pigment particles in the plaster.
The chemical processes are as follows:
calcination of limestone in a lime kiln: CaCO3 → CaO + CO2
slaking of quicklime: CaO + H2O → Ca(OH)2
setting of the lime plaster: Ca(OH)2 + CO2 → CaCO3 + H2O
In painting buon fresco, a rough underlayer called the arriccio is added to the whole area to be painted and allowed to dry for some days. Many artists sketched their compositions on this underlayer, which would never be seen, in a red pigment called sinopia, a name also used to refer to these under-paintings.
Official source
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