In physics, polaritons pəˈlærᵻtɒnz,_poʊ- are quasiparticles resulting from strong coupling of electromagnetic waves with an electric or magnetic dipole-carrying excitation. They are an expression of the common quantum phenomenon known as level repulsion, also known as the avoided crossing principle. Polaritons describe the crossing of the dispersion of light with any interacting resonance. To this extent polaritons can also be thought of as the new normal modes of a given material or structure arising from the strong coupling of the bare modes, which are the photon and the dipolar oscillation. The polariton is a bosonic quasiparticle, and should not be confused with the polaron (a fermionic quasiparticle), which is an electron plus an attached phonon cloud.
Whenever the polariton picture is valid (i.e., when the weak coupling limit is an invalid approximation), the model of photons propagating freely in crystals is insufficient. A major feature of polaritons is a strong dependency of the propagation speed of light through the crystal on the frequency of the photon. For exciton-polaritons, a wealth of experimental results on various aspects have been gained in the case of copper(I) oxide.
Oscillations in ionized gases were observed by Lewi Tonks and Irving Langmuir in 1929. Polaritons were first considered theoretically by Kirill Borisovich Tolpygo. They were termed light-excitons in Soviet scientific literature. That name was suggested by Solomon Isaakovich Pekar, but the term polariton, proposed by John Hopfield, was adopted. Coupled states of electromagnetic waves and phonons in ionic crystals and their dispersion relation, now known as phonon polaritons, were obtained by Tolpygo in 1950 and, independently, by Huang Kun in 1951. Collective interactions were published by David Pines and David Bohm in 1952, and plasmons were described in silver by Herbert Fröhlich and H. Pelzer in 1955. R.H Ritchie predicted surface plasmons in 1957, then Ritchie and H.B. Eldridge published experiments and predictions of emitted photons from irradiated metal foils in 1962.
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