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A single spectra library was used to monitor on-line, by mid-infrared spectroscopy, nine different batch cultures of Escherichia coli performed with various medium compositions, including chemically complex formulations. Whereas the classic chemometrics ap ...
Geographic Information Science methods and tools are likely to help to extract useful and so far unknown information from large spatially explicit genetic datasets to understand the distribution of diversity among and within sheep and goat breeds. Consider ...
Extensive research is being devoted to the analysis and application of cellular solids for the design of innovative structural components. The chiral geometry in particular features a unique mechanical behavior which is here exploited for the design of 2D ...
Fluorescence correlation spectroscopy (FCS) has emerged as a powerful technique for measuring low concentrations of fluorescent molecules and their diffusion constants. In FCS, the experimental data is conventionally fit using standard local search techniq ...
This thesis is a contribution to financial statistics. One of the principal concerns of investors is the evaluation of portfolio risk. The notion of risk is vague, but in finance it is always linked to possible losses. In this thesis, we present some measu ...
Five increasingly sophisticated aromaticity indexes, based on nucleus-independent chem. shifts (NICS), were evaluated against a uniform set of arom. stabilization energies (ASE) for 75 mono- and polyheterocyclic five-membered rings. While acceptable statis ...
Using a density-functional approach, we investigate the reactivity of supported metal nanoclusters. We focus on the sequential adsorption of N-2 molecules on a Fe nanocluster supported by an MgO substrate. For an increasing number of N atoms preadsorbed on ...
In large-eddy simulations (LESs) of atmospheric reacting flows, homogeneous and instantaneous mixing of reactants within a grid-cell is usually assumed. However, highly reactive species are often segregated or pre-mixed at small scales. In this paper, we p ...
The goal of our project (HES-SO n°11246) is to develop chemometric methods that enhance the development of chemical reactions. Semi-batch experiments are performed using a fully automated chemical reactor. Real-time analytical data, infrared (IR) spectra f ...