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Resonance Raman scattering studies of a complete dye-sensitized solar cell (DSC) including iodine and lithium iodide in the electrolyte indicate that triiodide (I3-) exchange the SCN- ligand of the dye bis(tetrabutylammonium) cis-bis(thiocyanato)bis(2,2'-b ...
Reliable split C(V) measurements are shown to be feasible on ultra-thin oxides (down to 1.2 nm) by using relatively small area MOSFETs (typically 100 mum(2)). To this end, specific correction procedures for parasitic parallel capacitances and gate leakage ...
A new series of iridium(III) mixed ligand complexes TBA[Ir(ppy)2(CN)2] (1), TBA[Ir(ppy)2(NCS)2] (2), TBA[Ir(ppy)2(NCO)2] (3), and [Ir(ppy)2(acac) (4) (ppy = 2-phenylpyridine; acac ...
We have measured the resonant inelastic x-ray scattering (RIXS) spectra at the Cu L-3 edge in a variety of cuprates. Exploiting a considerably improved energy resolution (0.8 eV) we recorded significant dependencies on the sample composition and orientatio ...
Individual MO (MO) contributions to the magnetic shielding of atoms as well as to the nucleus-independent chem. shifts (NICS) of arom. compds. can be computed by the widely used gauge-including AO (GIAO) method. Detailed analyses of magnetic shielding MO-N ...
The synthesis of the potentially nonadentate ligand 1,4,7-tris[(6-carboxypyridin-2-yl)methyl]-1,4,7-triazacyclononane (H3tpatcn), a new derivative of 1,4,7-triazacyclononane N-functionalised with three pyridinecarboxylate arms, is described. The complexes ...
By deliberately causing degrdn. of components in a dye-sensitized solar cell the authors have studied failure mechanisms of such cells. The dye, bis(tetrabutylammonium) cis-bis(thiocyanato)bis(2,2'-bipyridine-4-carboxylic acid, 4'-carboxylate)ruthenium(II) ...
The photophysical properties of the triple-stranded dimetallic helicates [Ln2(LC−2H)3]·H2O (Ln = Nd, Sm, Dy, Yb) are determined in water and D2O solutions, and energy transfer processes are modeled for SmIII. The luminescence of NdIII, SmIII, and YbIII is ...
Carbamoyl phosphate (CP) has been implicated as an educt for the synthesis of the CO and CN ligands of the metal centre of [NiFe]-hydrogenases in Escherichia coli, since CP synthetase mutants (carAB) are unable to generate active hydrogenases due to a bloc ...
The photophysical properties of the triple-stranded dimetallic helicates [Ln2(LC−2H)3]·H2O (Ln = Nd, Sm, Dy, Yb) are determined in water and D2O solutions, and energy transfer processes are modeled for SmIII. The luminescence of NdIII, SmIII, and YbIII is ...