Publications related to Ligand field theory

Electronic Phase Separation and Dramatic Inverse Band Renormalization in the Mixed-Valence Cuprate LiCu2O2

Marco Grioni, Arnaud Magrez, Helmuth Berger, Philippe Bugnon, Luca Moreschini, Simon Karl Moser, Gianmarco Gatti

We measured, by angle-resolved photoemission spectroscopy, the electronic structure of LiCu2O2, a mixed-valence cuprate where planes of Cu(I) (3d(10)) ions are sandwiched between layers containing one-dimensional edge-sharing Cu(II) (3d(9)) chains. We find ...

Amer Physical Soc2017

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Qian Wang, Jieping Zhu, Wangqing Kong

Pd-catalyzed intramolecular asymmetric carbopalladation of N-aryl acrylamides followed by reduction of C(sp3)-Pd intermediate using diboron–water as a hydride source afforded enantioenriched 3,3-disubstituted oxindoles in high yields and enantioselectiviti ...

Wiley-Blackwell2017

Acylated heptapeptide binds albumin with high affinity and application as tag furnishes long-acting peptides

Christian Heinis, Alessandro Zorzi, Jonas Alfred Karl Wilbs, Simon Jan Middendorp

The rapid renal clearance of peptides in vivo limits this attractive platform for the treatment of a broad range of diseases that require prolonged drug half-lives. An intriguing approach for extending peptide circulation times works through a 'piggy-back' ...

2017

Sampling and Energy Evaluation Challenges in Ligand Binding Protein Design

Kai Johnsson, Alberto Schena

The steroid hormone 17α-hydroxylprogesterone (17-OHP) is a biomarker for congenital adrenal hyperplasia and hence there is considerable interest in sensor development towards this compound. We used computational protein design to generate protein models wi ...

Cold Spring Harbor Laboratory Press2017

A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes

Nicolai Cramer, Matthew Wodrich, Benoît Daniel Bertrand Audic, Gints Smits

The electronic and steric properties of tailored cyclopentadienyl (Cp) ligands are powerful handles to modulate the catalytic properties of their metal complexes. This requires the individual preparation, purification and storage of each ligand/metal combi ...

2017

PdII2L4-type coordination cages up to three nanometers in size

Rosario Scopelliti, Kay Severin, Suzanne Maria Jansze, Matthew David Wise

The utilization of large ligands in coordination-based self-assembly represents an attractive strategy for the construction of supramolecular assemblies more than two nanometers in size. However, the implementation of this strategy is hampered by the fact ...

2017

Synthesis and Photophysical Characterization of Cyclometalated Ruthenium Complexes with N-Heterocyclic Carbene Ligands

Mohammad Khaja Nazeeruddin, Iwan Zimmermann, Sadig Aghazada, Valeriu Scutelnic

In the search of new ligand environment for the ruthenium(II) complexes with pyridine-type ligands, we developed seven new cyclometalated ruthenium complexes with N-heterocyclic carbenes (NHCs). In a two-step procedure, we synthesized complexes with the ge ...

American Chemical Society2017

Chiral N-Heterocyclic Carbene Ligand Enabled Nickel(0)-Catalyzed Enantioselective Three-Component Couplings as Direct Access to Silylated Indanols

Nicolai Cramer, Joachim Sven Ernst Ahlin

An enantioselective nickel(0)-catalyzed reductive three-component coupling between aromatic aldehydes, norbornenes, and silanes affords directly silyl-protected indanol derivatives. A new bulky chiral C-2-symmetric NHC (NHC = N-heterocyclic carbene) ligand ...

American Chemical Society2016

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Ligand field theory

Electronic Phase Separation and Dramatic Inverse Band Renormalization in the Mixed-Valence Cuprate LiCu2O2

CO2 as hydrogen vector - Transition metal diamine catalysts for selective HCOOH dehydrogenation

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Acylated heptapeptide binds albumin with high affinity and application as tag furnishes long-acting peptides

Sampling and Energy Evaluation Challenges in Ligand Binding Protein Design

A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes

PdII2L4-type coordination cages up to three nanometers in size

Direct enhancement of nitrogen-15 targets at high-field by fast ADAPT-SABRE

Synthesis and Photophysical Characterization of Cyclometalated Ruthenium Complexes with N-Heterocyclic Carbene Ligands

Chiral N-Heterocyclic Carbene Ligand Enabled Nickel(0)-Catalyzed Enantioselective Three-Component Couplings as Direct Access to Silylated Indanols

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Sampling and Energy Evaluation Challenges in Ligand Binding Protein Design

PdII2L4-type coordination cages up to three nanometers in size

Chiral N-Heterocyclic Carbene Ligand Enabled Nickel(0)-Catalyzed Enantioselective Three-Component Couplings as Direct Access to Silylated Indanols

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Electronic Phase Separation and Dramatic Inverse Band Renormalization in the Mixed-Valence Cuprate LiCu2O2

Acylated heptapeptide binds albumin with high affinity and application as tag furnishes long-acting peptides

A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes

Direct enhancement of nitrogen-15 targets at high-field by fast ADAPT-SABRE

CO2 as hydrogen vector - Transition metal diamine catalysts for selective HCOOH dehydrogenation

Synthesis and Photophysical Characterization of Cyclometalated Ruthenium Complexes with N-Heterocyclic Carbene Ligands