Summary
Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the form of magnetite (Fe3O4, 72.4% Fe), hematite (Fe2O3, 69.9% Fe), goethite (FeO(OH), 62.9% Fe), limonite (FeO(OH)·n(H2O), 55% Fe) or siderite (FeCO3, 48.2% Fe). Ores containing very high quantities of hematite or magnetite, typically greater than about 60% iron, are known as natural ore or direct shipping ore, and can be fed directly into iron-making blast furnaces. Iron ore is the raw material used to make pig iron, which is one of the main raw materials to make steel—98% of the mined iron ore is used to make steel. In 2011 the Financial Times quoted Christopher LaFemina, mining analyst at Barclays Capital, saying that iron ore is "more integral to the global economy than any other commodity, except perhaps oil". Metallic iron is virtually unknown on the surface of the Earth except as iron-nickel alloys from meteorites and very rare forms of deep mantle xenoliths. Some iron meteorites are thought to have originated from accreted bodies 1,000 km in diameter or larger The origin of iron can be ultimately traced to the formation through nuclear fusion in stars, and most of the iron is thought to have originated in dying stars that are large enough to collapse or explode as supernovae. Although iron is the fourth-most abundant element in the Earth's crust, composing about 5%, the vast majority is bound in silicate or, more rarely, carbonate minerals (for more information, see iron cycle). The thermodynamic barriers to separating pure iron from these minerals are formidable and energy-intensive; therefore, all sources of iron used by human industry exploit comparatively rarer iron oxide minerals, primarily hematite. Prior to the industrial revolution, most iron was obtained from widely available goethite or bog ore, for example, during the American Revolution and the Napoleonic Wars.
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