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Concept
Langmuir–Blodgett film
Summary
A Langmuir–Blodgett (LB) film is a nanostructured system formed when Langmuir films—or Langmuir monolayers (LM)—are transferred from the liquid-gas interface to solid supports during the vertical passage of the support through the monolayers. LB films can contain one or more monolayers of an organic material, deposited from the surface of a liquid onto a solid by immersing (or emersing) the solid substrate into (or from) the liquid. A monolayer is adsorbed homogeneously with each immersion or emersion step, thus films with very accurate thickness can be formed. This thickness is accurate because the thickness of each monolayer is known and can therefore be added to find the total thickness of a Langmuir–Blodgett film.
The monolayers are assembled vertically and are usually composed either of amphiphilic molecules (see chemical polarity) with a hydrophilic head and a hydrophobic tail (example: fatty acids) or nowadays commonly of nanoparticles.
Langmuir–Blodgett films are named after Irving Langmuir and Katharine B. Blodgett, who invented this technique while working in Research and Development for General Electric Co.
Advances to the discovery of LB and LM films began with Benjamin Franklin in 1773 when he dropped about a teaspoon of oil onto a pond. Franklin noticed that the waves were calmed almost instantly and that the calming of the waves spread for about half an acre. What Franklin did not realize was that the oil had formed a monolayer on top of the pond surface. Over a century later, Lord Rayleigh quantified what Benjamin Franklin had seen. Knowing that the oil, oleic acid, had spread evenly over the water, Rayleigh calculated that the thickness of the film was 1.6 nm by knowing the volume of oil dropped and the area of coverage.
With the help of her kitchen sink, Agnes Pockels showed that area of films can be controlled with barriers. She added that surface tension varies with contamination of water. She used different oils to deduce that surface pressure would not change until area was confined to about 0.
Official source
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