Self-phase modulation (SPM) is a nonlinear optical effect of light–matter interaction. An ultrashort pulse of light, when travelling in a medium, will induce a varying refractive index of the medium due to the optical Kerr effect. This variation in refractive index will produce a phase shift in the pulse, leading to a change of the pulse's frequency spectrum. Self-phase modulation is an important effect in optical systems that use short, intense pulses of light, such as lasers and optical fiber communications systems. Self-phase modulation has also been reported for nonlinear sound waves propagating in biological thin films, where the phase modulation results from varying elastic properties of the lipid films. The evolution along distance z of the equivalent lowpass electric field A(z) obeys the nonlinear Schrödinger equation which, in absence of dispersion, is: with j the imaginary unit and γ the nonlinear coefficient of the medium. The cubic nonlinear term on the right hand side is called Kerr effect, and is multiplied by -j according to the engineer's notation used in the definition of Fourier transform. The power of the electric field is invariant along z, since: with * denoting conjugation. Since the power is invariant, the Kerr effect can manifest only as a phase rotation. In polar coordinates, with , it is: such that: The phase φ at coordinate z therefore is: Such a relation highlights that SPM is induced by the power of the electric field. In presence of attenuation α the propagation equation is: and the solution is: where is called effective length and is defined by: Hence, with attenuation the SPM does not grow indefinitely along distance in a homogeneous medium, but eventually saturates to: In presence of dispersion the Kerr effect manifests as a phase shift only over short distances, depending on the amount of dispersion. For an ultrashort pulse with a Gaussian shape and constant phase, the intensity at time t is given by I(t): where I0 is the peak intensity, and τ is half the pulse duration.

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Ultrashort pulse
In optics, an ultrashort pulse, also known as an ultrafast event, is an electromagnetic pulse whose time duration is of the order of a picosecond (10−12 second) or less. Such pulses have a broadband optical spectrum, and can be created by mode-locked oscillators. Amplification of ultrashort pulses almost always requires the technique of chirped pulse amplification, in order to avoid damage to the gain medium of the amplifier. They are characterized by a high peak intensity (or more correctly, irradiance) that usually leads to nonlinear interactions in various materials, including air.
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The Kerr effect, also called the quadratic electro-optic (QEO) effect, is a change in the refractive index of a material in response to an applied electric field. The Kerr effect is distinct from the Pockels effect in that the induced index change is directly proportional to the square of the electric field instead of varying linearly with it. All materials show a Kerr effect, but certain liquids display it more strongly than others. The Kerr effect was discovered in 1875 by Scottish physicist John Kerr.
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