Polymetallic nodules, also called manganese nodules, are mineral concretions on the sea bottom formed of concentric layers of iron and manganese hydroxides around a core. As nodules can be found in vast quantities, and contain valuable metals, deposits have been identified as a potential economic interest.
Nodules vary in size from tiny particles visible only under a microscope to large pellets more than across. However, most nodules are between in diameter, about the size of hen's eggs or potatoes. Their surface textures vary from smooth to rough. They frequently have botryoidal (mammillated or knobby) texture and vary from spherical in shape to typically oblate, sometimes prolate, or are otherwise irregular. The bottom surface, buried in sediment, is generally rougher than the top due to a different type of growth.
Nodules lie on the seabed sediment, often partly or completely buried. They vary greatly in abundance, in some cases touching one another and covering more than 70% of the sea floor surface. The total amount of polymetallic nodules on the sea floor was estimated at 500 billion tons by Alan A. Archer of the London Geological Museum in 1981.
Polymetallic nodules are found in both shallow (e.g. the Baltic Sea) and deeper waters (e.g. the central Pacific), even in lakes, and are thought to have been a feature of the seas and oceans at least since the deep oceans were oxygenated in the Ediacaran period over 540 million years ago.
Polymetallic nodules were discovered in 1868 in the Kara Sea, in the Arctic Ocean of Siberia. During the scientific expeditions of HMS Challenger (1872–1876), they were found to occur in most oceans of the world.
Their composition varies by location, and sizeable deposits have been found in the following areas:
Penrhyn Basin within the Cook Islands.
North central Pacific Ocean in a region called the Clarion Clipperton Zone (CCZ) roughly midway between Hawaii and Clipperton Islands.
Peru Basin in the southeast Pacific, and
Southern tropical Indian Ocean in a region termed the Indian Ocean Nodule Field (IONF) roughly 500 km SE of Diego Garcia Island.
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