Concept

Technetium

Related publications (53)

Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems

Paul Joseph Dyson, Farzaneh Fadaei Tirani, Mouna Hadiji

Structural and electronic factors are crucial to rationalizethedifferent N,O or N,N chelating coordination of pyrazolones containinga pyridine ring. The reactivity of proligand 3-phenyl-1-(pyridin-2-yl)-5-pyrazolone(HLpy,ph) with the (arene)Ru(II) fragment ...

AMER CHEMICAL SOC2023

A fluoropolymer bifunctional solid membrane interface for improving the discharge duration in aqueous Al-air batteries

Thi Ha My Pham, Liping Zhong, Manhui Wei, Meixia Zhang

Herein, a fluoropolymer bifunctional solid membrane interface (SMI) for an aqueous Al-air battery is proposed, which inhibits anodic self-corrosion, while concurrently reducing the accumulation of undesirable by-products. A battery using the SMI exhibits a ...

ROYAL SOC CHEMISTRY2023

A concept for the extraction of the most refractory elements at CERN-ISOLDE as carbonyl complex ions

We introduce a novel thick-target concept tailored to the extraction of refractory 4d and 5d transition metal radionuclides of molybdenum, technetium, ruthenium and tungsten for radioactive ion beam production. Despite the more than 60-year old history of ...

2022

Visible light photoredox-catalysed remote C-H functionalisation enabled by 1,5-hydrogen atom transfer (1,5-HAT)

Qian Wang, Jieping Zhu, Weisi Guo

The generation of heteroatom-centred radicals (X), followed by intramolecular 1,5-hydrogen atom transfer (1,5-HAT) and the functionalisation of the translocated carbon-centred radicals, is the basic mechanism of the classic Hofmann-Loffler-Freytag (HLF) re ...

2021

High-Efficiency Deep-Red Light-Emitting Electrochemical Cell Based on a Trinuclear Ruthenium(II)-Silver(I) Complex

Mohammad Khaja Nazeeruddin

Turn-on time is a key factor for lighting devices to be of practical application. To decrease the turn-on time value of a deep-red light-emitting electrochemical cells (DR-LECs), two novel approaches based on molecularly engineered ruthenium phenanthroimid ...

AMER CHEMICAL SOC2021

Evaluation of materials for iodine and technetium immobilization through sorption and redox-driven processes

Wendy Lee Queen, Daniel Teav Sun

Radioactive iodine-129 (I-129) and technetium-99 (Tc-9(9)) pose a risk to groundwater due to their long half-lives, toxicity, and high environmental mobility. Based on literature reviewed in Moore et al. (2019) and Pearce et aL (2019), natural and engineer ...

ELSEVIER2020

Circularly Polarized Transmitarray Antenna for CubeSat Intersatellite Links in K-Band

Anja Skrivervik, Miroslav Veljovic

A circularly polarized transmitarray antenna based on aperture-coupled patches is presented for CubeSat intersatellite-link applications in K-band. The concept of aperture coupling simplifies the design of transmitarray elements, as it omits the need for m ...

2020

Thermomechanical Nanocutting of 2D Materials

Jürgen Brugger, Giovanni Boero, Xia Liu, Ana Conde Rubio, Samuel Tobias Howell

Atomically thin materials, such as graphene and transition metal dichalcogenides, are promising candidates for future applications in micro/nanodevices and systems. For most applications, functional nanostructures have to be patterned by lithography. Devel ...

2020

Role of JETPEAK database in validation of synthetic neutron camera diagnostics and ASCOT- AFSI fast particle and fusion product calculation chain in JET

Henri Weisen

JETPEAK is a comprehensive stationary-state database and a work environment for JET diagnostics data, processed data and simulations suitable for a wide variety of analytical tasks. It enables systematic modelling and efficient interpretation of synthetic ...

IOP PUBLISHING LTD2019

Improvements in physics models of AFSI-ASCOT-based synthetic neutron diagnostics at JET

Henri Weisen

New development steps of AFSI-ASCOT based synthetic neutron diagnostics and validation at JET are reported in this contribution. Synthetic neutron diagnostics are important not only in existing tokamaks, where they are used to interpret experimental data, ...

ELSEVIER SCIENCE SA2019

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