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Concept
Hydrogen spectral series
Summary
The emission spectrum of atomic hydrogen has been divided into a number of spectral series, with wavelengths given by the Rydberg formula. These observed spectral lines are due to the electron making transitions between two energy levels in an atom. The classification of the series by the Rydberg formula was important in the development of quantum mechanics. The spectral series are important in astronomical spectroscopy for detecting the presence of hydrogen and calculating red shifts.
A hydrogen atom consists of an electron orbiting its nucleus. The electromagnetic force between the electron and the nuclear proton leads to a set of quantum states for the electron, each with its own energy. These states were visualized by the Bohr model of the hydrogen atom as being distinct orbits around the nucleus. Each energy level, or electron shell, or orbit, is designated by an integer, n as shown in the figure. The Bohr model was later replaced by quantum mechanics in which the electron occupies an atomic orbital rather than an orbit, but the allowed energy levels of the hydrogen atom remained the same as in the earlier theory.
Spectral emission occurs when an electron transitions, or jumps, from a higher energy state to a lower energy state. To distinguish the two states, the lower energy state is commonly designated as n′, and the higher energy state is designated as n. The energy of an emitted photon corresponds to the energy difference between the two states. Because the energy of each state is fixed, the energy difference between them is fixed, and the transition will always produce a photon with the same energy.
The spectral lines are grouped into series according to n′. Lines are named sequentially starting from the longest wavelength/lowest frequency of the series, using Greek letters within each series. For example, the 2 → 1 line is called "Lyman-alpha" (Ly-α), while the 7 → 3 line is called "Paschen-delta" (Pa-δ).
There are emission lines from hydrogen that fall outside of these series, such as the 21 cm line.
Official source
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