Concept
Electron acceptor
Related publications (141)
Donor-Acceptor-Donor "Hot Exciton" Triads for High Reverse Intersystem Crossing in OLEDs
Sergio Vela Llausi, Maria Fumanal Quintana, Yanan Zhu
Hot exciton materials have the potential to improve the quantum efficiency of organic light-emitting diodes (OLEDs) by promoting high reversed intersystem crossing (hRISC) between a high-lying triplet (T-n, n >= 2) and a radiative singlet (S-m). In recent ...
WILEY-V C H VERLAG GMBH2022Conditional essentiality of a complex I-like enzyme in strict anaerobes: the case of Desulfitobacterium
Christof Holliger, Julien Maillard, Romain Hamelin, Mathilde Stéphanie Willemin, Florence Armand
Respiratory complex I is a well-known player in aerobic respiration; it couples the transfer of two electrons from NADH to ubiquinone alongside with proton pumping. Bacterial complex I is usually composed of fourteen subunits forming three different module ...
2021Insights into the microbial reduction of pentavalent and hexavalent uranium species by Shewanella oneidensis MR-1
Margaux Camille Andréa Molinas
Decades of uranium-related activities such as ore mining, nuclear power generation, weapon manufacture, storage of nuclear wastes, have contributed to the release of U in the environment. U occurrence is concerning, since in surface environments, U is typi ...
EPFL2021Pushing the Limits of the Donor-Acceptor Copolymer Strategy for Intramolecular Singlet Fission
Donor-acceptor (D-A) copolymers have shown great potential for intramolecular singlet fission (iSF). Nonetheless, very few design principles exist for optimizing these systems for iSF, with very little knowledge about how to engineer them for this purpose. ...
AMER CHEMICAL SOC2021Organohalide respiration: variations on a common theme
Christof Holliger, Julien Maillard, Mathilde Stéphanie Willemin, Lorenzo Cimmino
Organohalide respiration (OHR) is a bacterial anaerobic respiratory metabolism that makes use of halogenated organic compounds as terminal electron acceptors. While organohalogens have been initially thought to be mainly from anthropogenic origin, thousand ...
2021Delineating Conformation Control in the Photophysical Behaviour of a Molecular Donor-Acceptor-Donor Triad
Mechanochromic luminescent materials, exhibiting a change in luminescence behavior under external stimuli have emerged as one of the promising candidates for upcoming efficient OLEDs. Recently mechanochromic luminescence was reported in a donor-acceptor-do ...
WILEY-V C H VERLAG GMBH2021The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface
H2O2 is a versatile chemical and can be generated by the oxygen reduction reaction (ORR) in proton donor solution in molecular solvents or room temperature ionic liquids (IL). We investigated this reaction at interfaces formed by eleven hydrophobic ILs and ...
2021In Situ Biostimulation of Cr(VI) Reduction in a Fast-Flowing Oxic Aquifer
Rizlan Bernier-Latmani, Daniel Scott Alessi
Hexavalent chromium is among the most common and hazardous inorganic contaminants in soils and groundwater. A promising in situ bioremediation approach is the delivery of electron donors to stimulate microbially mediated Cr(VI) reduction, producing relativ ...
AMER CHEMICAL SOC2020Hybrid Transcriptional Regulators for the Screening of Target DNA Motifs in Organohalide-Respiring Bacteria
Christof Holliger, Julien Maillard, Mathilde Stéphanie Willemin, Marie Vingerhoets
The bioremediation of persistent organohalide molecules under anoxic conditions mostly relies on the bacterial process called organohalide respiration (OHR). Organohalide-respiring bacteria (OHRB) are phylogenetically diverse anaerobic bacteria that share ...
2020Carbon dioxide reduction by lanthanide(iii) complexes supported by redox-active Schiff base ligands
Rosario Scopelliti, Marinella Mazzanti, Davide Toniolo, Nadir Jori
Here we have explored the ability of Schiff bases to act as electron reservoirs and to enable the multi-electron reduction of small molecules by lanthanide complexes. We report the reductive chemistry of the Ln(iii) complexes of the tripodal heptadentate S ...
ROYAL SOC CHEMISTRY2020