Concept
Uranium
Related publications (114)
Implementing Multi-Electron Transfer Strategies in Uranium Chemistry
In the last decades, the activation of small molecules has attracted increasing attention for their use as cheap and abundant feedstock. Low-oxidation state uranium complexes have displayed high reactivity towards small molecules thanks to their unique pro ...
EPFL2023A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes
Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic
Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...
2023Persistence of the isotopic signature of pentavalent uranium in magnetite
Rizlan Bernier-Latmani, Barbora Bártová, Zezhen Pan
Uranium isotopic signatures can be harnessed to monitor the reductive remediation of subsurface contamination or to reconstruct paleo-redox environments. However, the mechanistic underpinnings of the isotope fractionation associated with U reduction remain ...
2022