Feldspar (sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight.
Feldspars crystallize from magma as both intrusive and extrusive igneous rocks and are also present in many types of metamorphic rock. Rock formed almost entirely of calcic plagioclase feldspar is known as anorthosite. Feldspars are also found in many types of sedimentary rocks.
The feldspar group of minerals consists of tectosilicates, silicate minerals in which silicon ions are linked by shared oxygen ions to form a three-dimensional network. Compositions of major elements in common feldspars can be expressed in terms of three endmembers:
potassium feldspar (K-spar) endmember KAlSi_3O_8
albite endmember NaAlSi_3O_8
anorthite endmember CaAl_2Si_2O_8
Solid solutions between K-feldspar and albite are called alkali feldspar. Solid solutions between albite and anorthite are called plagioclase, or, more properly, plagioclase feldspar. Only limited solid solution occurs between K-feldspar and anorthite, and in the two other solid solutions, immiscibility occurs at temperatures common in the crust of the Earth. Albite is considered both a plagioclase and alkali feldspar.
The ratio of alkali feldspar to plagioclase feldspar, together with the proportion of quartz, is the basis for the QAPF classification of igneous rock. Calcium-rich plagioclase is the first feldspar to crystallize from cooling magma, but the plagioclase becomes increasingly sodium-rich as crystallization continues. This defines the continuous Bowen's reaction series. K-feldspar is the final feldspar to crystallize from the magma.
Alkali feldspars are grouped into two types: those containing potassium in combination with sodium, aluminium, or silicon; and those where potassium is replaced by barium.
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