A carbon star (C-type star) is typically an asymptotic giant branch star, a luminous red giant, whose atmosphere contains more carbon than oxygen. The two elements combine in the upper layers of the star, forming carbon monoxide, which consumes most of the oxygen in the atmosphere, leaving carbon atoms free to form other carbon compounds, giving the star a "sooty" atmosphere and a strikingly ruby red appearance. There are also some dwarf and supergiant carbon stars, with the more common giant stars sometimes being called classical carbon stars to distinguish them.
In most stars (such as the Sun), the atmosphere is richer in oxygen than carbon. Ordinary stars not exhibiting the characteristics of carbon stars but cool enough to form carbon monoxide are therefore called oxygen-rich stars.
Carbon stars have quite distinctive spectral characteristics, and they were first recognized by their spectra by Angelo Secchi in the 1860s, a pioneering time in astronomical spectroscopy.
By definition carbon stars have dominant spectral Swan bands from the molecule C2. Many other carbon compounds may be present at high levels, such as CH, CN (cyanogen), C3 and SiC2. Carbon is formed in the core and circulated into its upper layers, dramatically changing the layers' composition. In addition to carbon, S-process elements such as barium, technetium, and zirconium are formed in the shell flashes and are "dredged up" to the surface.
When astronomers developed the spectral classification of the carbon stars, they had considerable difficulty when trying to correlate the spectra to the stars' effective temperatures. The trouble was with all the atmospheric carbon hiding the absorption lines normally used as temperature indicators for the stars.
Carbon stars also show a rich spectrum of molecular lines at millimeter wavelengths and submillimeter wavelengths. In the carbon star CW Leonis more than 50 different circumstellar molecules have been detected. This star is often used to search for new circumstellar molecules.
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