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One of the major challenges faced by organic chemistry is the efficient synthesis of increasingly complex molecules. Since October 2007, the Laboratory of Catalysis and Organic Synthesis (LCSO) at EPFL has been working on the development of catalytic react ...
Three different types of nanocryst., N-doped TiO2 electrodes were synthesized using several nitrogen dopants through wet methods. The obtained nanocryst., N-doped TiO2 electrodes possessed different crystallite sizes, surface areas, and N-doping amts. Char ...
This thesis is divided in seven main chapters including an introduction about the state of the art in the field, four main chapters describing the main part of the work, a short insight on the implications of the presented results for other research projec ...
In this work we explored the possibility of obtaining nanocrystalline (Y0.5Lu0.5)2O3 powders, doped with europium and co-doped with praseodium, employing polymer complex solution synthesis. Polyethylene glycol, with average molecular weight 200, served bot ...
The reaction mechanism on the formation of the hydrosulfido complex [Re(SH)(CO)(3)(bipy)] via the reaction of [Re(OH)(CO)(3)(bipy)] with carbon disulfide was theoretically investigated at the B3LYP/6-31+G(d, p) (LANL2DZ+f for Re) level of theory taking int ...
We present a comparative study of ultrafast photoexcited state relaxation in pentacene single crystals and in pure and C-60-doped pentacene films using optical pump-probe spectroscopy. The photoinduced absorption spectra in pentacene crystals is consistent ...
Doping and temperature dependent studies of optical phonon modes in Fe-122 pnictides are performed using Raman scattering experiments and compared with model calculations to elucidate the role of electron-phonon and spin-phonon interaction in this family o ...
Photostructurable polymers, such as SU-8, have large potential impact on the field of MEMS/NEMS, allowing simple fabrication of plastic MEMS/NEMS devices with nearly vertical sidewalls and high aspect ratios using standard photolithographic procedures. Fun ...
In dye-sensitized solar cells an efficient transfer of holes from the oxidized dye to the contact is necessary, which in solid-state dye-sensitized solar cells is performed by hole-conductor mols. In this report we use photoinduced absorption and transient ...
Chemical doping is an important strategy to alter the charge-transport properties of both molecular and polymeric organic semiconductors that find widespread application in organic electronic devices. We report on the use of a new class of Co(III) complexe ...