Diesel fuel | EPFL Graph Search

Diesel fuel ˈdiːzəl, also called diesel oil or historically heavy oil, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and then injection of fuel. Therefore, diesel fuel needs good compression ignition characteristics. The most common type of diesel fuel is a specific fractional distillate of petroleum fuel oil, but alternatives that are not derived from petroleum, such as biodiesel, biomass to liquid (BTL) or gas to liquid (GTL) diesel are increasingly being developed and adopted. To distinguish these types, petroleum-derived diesel is sometimes called petrodiesel in some academic circles. In many countries, diesel fuel is standardised. For example, in the European Union, the standard for diesel fuel is EN 590. Ultra-low-sulfur diesel (ULSD) is a diesel fuel with substantially lowered sulfur contents. As of 2016, almost all of the

Emission reduction by targeted transient operations in three-way catalysts for heavy-duty natural gas applications

Moyu Wang

To curb the severe effects of climate change, our society needs to radically reduce its CO2 footprint. For the heavy-duty sector, where electrification is difficult, alternative fuels can be the solution. Methane-fueled engines have lower energy-specific CO2 emissions than conventional Diesel-fueled engines. Furthermore, they have the potential of becoming carbon-neutral, when combined with bio-methane/synthetic methane. However, oxidation of unburnt methane in the exhaust gas poses a challenge for aftertreatment systems. The aim of this thesis is to investigate the mechanism of methane abatement and to reveal methods to reduce methane and other hazardous gas emissions. The majority of the experiments were conducted directly on an engine test bench, which is rarely seen in studies focusing on catalytic reaction pathways. Initial investigations focused on methane abatement under steady state and Î»-step transitions. Under steady state, the presence of oxygen was identified as a prerequisite for methane conversion. Reacting with oxygen is the only methane conversion pathway. However, after step transition from oxygen excess conditions (slightly lean) to oxygen-poor conditions (slightly rich), high methane conversion was observed under rich conditions with no oxygen available. This high conversion was attributed to steam reforming (SR), which was activated by the step transition. The SR reaction rate decreased over time when staying at rich conditions, until full deactivation. Investigations in the lab-scale model gas reactor confirmed this analysis. In addition, the reason for SR deactivation was identified by DRIFTS measurements as the accumulation of carbonates on the catalytic surface, blocking the active sites. Based on the identified importance of the SR reaction, targeted Î» oscillations across stoichiometry were introduced, in order to repeatably activate SR and achieve sustainable high methane conversion. During the rich parts of the oscillations, methane was converted via SR, while, during lean parts, the carbonates were periodically removed from the catalyst surface. With these oscillations, methane conversion has been significantly improved, in comparison to steady state. In parallel, a numerical model has been developed in order to simulate the catalyst behavior under oscillating conditions. The model provided insights on the reaction pathways and their distribution along the catalyst axis. The catalytic activity of the different Platinum-group metals has been investigated for the identified reactions. Various catalysts of different compositions were tested under cold start, Î» oscillations and quasi-steady state conditions. Both Pt and Pd activated SR reactions, however SR attenuation was faster in Pt catalysts. In lean conditions, Pt exhibited higher methane oxidation. Rh was identified as important for enhancing NOx reduction and lowering NH3 emissions. The combination of all three metals has improved the overall catalyst performances. In the final part of the thesis, a special aftertreatment system was investigated. It combines a Pd/Rh catalyst subject to stoichiometric conditions with a Pt oxidation catalyst subject to lean conditions. In the Pd/Rh catalyst, methane was removed via Î» oscillations. In the Pt catalyst, the remaining CO, H2 and NH3 were oxidized. The setup provided a novel perspective in reducing the overall environmental impacts.

EPFL2022

Steam and Co-Electrolysis Sensitivity Analysis on Ni-YSZ Supported Cells

Stefan Diethelm, Giorgio Rinaldi, Jan Van Herle

The present paper investigates the variation in performances in steam electrolysis and co-electrolysis of steam/CO2 on SOEC single cells.In electrolysis mode, a sensitivity analysis was performed looking in particular at the effects of temperature (750°C and 800°C) and inlet gas flows (from 100 to 200 Nml/min) on the performances. I-V characterization and EIS measurements at different current densities were carried out for each sequence. As expected, the increase of temperature has a positive impact on the performances, while the change of fuel flow slightly affects them. In co-electrolysis mode CO2 and H2O content was varied, keeping constant the total molar flow and the hydrogen fraction. Resulting plots demonstrate different ongoing processes favored at high current densities and high inlet CO2 molar fraction. In particular, reverse water-gas-shift reaction plays an important role on the overall balance of the gas species, and it directly depends on temperature and inlet fuel composition.

2015

PLASMA SHAPE AND FUELING DEPENDENCE ON THE SMALL ELMS REGIME IN TCV AND AUG

Benoît Labit, Roberto Maurizio, Antoine Pierre Emmanuel Alexis Merle, Pedro Andres Molina Cabrera, Umar Sheikh

A series of experiments has been conducted at AUG and TCV to disentangle the role of fueling, plasma triangularity and closeness to a double null (DN) configuration for the onset of the small ELM regime. At AUG, the role of the SOL density has been revisited. Indeed, it turns out that a large density SOL is not a sufficient condition to achieve the type-II (small) ELM regime. This has been demonstrated with a constant gas fueled plasma close to DN which has been progressively shifted down, relaxing therefore the closeness to DN at constant. As the plasma is moved down, Type-I ELMs are progressively restored, finally being the unique ELM regime. It is observed that not only the pedestal top profiles are unchanged, but also the SOL profiles remained unaffected by transition from Type-II to Type-I ELMs. We conclude that the separatrix density is not the unique key parameter and it is hypothesized that the local magnetic shear, modified by the closeness to DN, could play an important role. A small ELM regime with good confinement has been achieved at TCV, a full carbon machine featuring an open divertor. A systematic scan in the fueling rate has been done for both medium and high triangularity shapes. For the latter case, a configuration close to a DN configuration, the stored energy and the pedestal top pressure increase by 5% and 30% respectively compared to the medium triangularity case. For both shapes, as the D2 fueling is increased, the Type-I ELM frequency decreases and small ELMs are observed in between large ones. Finally for the high triangularity, at the maximum fueling rate, the large ELMs are fully suppressed and only the small ELMs remain. As observed in JET and AUG, the pedestal pressure degrades with increasing fueling, up to 40% for the high triangularity scenario, although the stored energy remains almost unchanged. It is also observed that, for both shapes, the density at the separatrix increases with the fueling rate, reaching ne,sep/nG ~0.3 at ne,av/nG~0.75. The small ELM regime at TCV is associated with a coherent mode at about 30 kHz seen by the magnetic probes located at the outboard midplane. The outer target heat loads from IR tomography are reduced by more than a factor of 5 when transiting towards the small ELM regime.