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Upon ionization of the P4S3I2 molecule with Ag[Al(OR)4], a highly reactive sulfonium cation P4S3I+ is generated (NMR simulated and assigned). At -80 °C this cation reacts with additional P4S3I2 to give either an iodophosphonium P4S3I3+ cation (NMR simulate ...
Nitrous oxide is the third most important gas contributing to global warming and its concentration in the atmosphere is still on the rise. Nitric acid production represents the largest source of N2O in the chemical industry, with a total annual emission of ...
The characterization of Fe/ZSM5 zeolite materials, the nature of Fe-sites active in N2O direct decomposition, as well as the rate limiting step are still a matter of debate. The mechanism of N2O decomposition on the binuclear oxo-hydroxo bridged extraframe ...
Interaction of N2O at low temps. (473-603 K) with Fe-ZSM-5 zeolites (Fe, 0.01-2.1 wt%) activated by steaming and/or thermal treatment in He at 1323 K was studied by the transient response method and temp.-programmed desorption (TPD). Diffuse reflectance IR ...
Recently, LTCC (low-temperature co-fired ceramic) technology has increasingly found applications beyond pure electronics, in fields such as microfluidics, sensors and actuators, due to the ease of shaping the tapes in the green (unfired) state. Accurate co ...
Vanadium substituted mesoporous AlPO have been synthesized using structure-directing surfactant under hydrothermal synthesis conditions. The presence of V in the framework of AlPO has been established by ESR, XPS, UV-vis DRS and ICP-AES measurements. This ...
The fractal dimensions of FeZSM-5 zeolites were used to characterize the change in their geometry depending on different post-synthesis treatments. The fractal dimension values were estimated from the Dubinin-Astakhov isotherms of nitrogen adsorption and r ...
One possibility for the removal of volatile organic compounds (VOCs) is catalytic oxidation. For the removal of VOCs in low concentration (≲ 3000 ppmv for propane) it is not possible to sustain the required oxidation temperature over the catalyst wit ...
Single crystals of self-synthesized mordenite−Na were used for incorporation of the cationic dye molecule thionin blue (C12H10N3S+). The planar organic molecule (7.5 × 15 Å), which fits into the large 12-membered ring channel of mordenite, was incorporated ...
We measured the elastic modulus of individual multiwalled carbon nanotubes (MWCNTs) grown by catalytic chemical vapor deposition (CVD) over a broad diameter range (10-25 nm). Alternating current (ac) dielectrophoresis was used for efficient tube deposition ...
