Boiling-point elevation describes the phenomenon that the boiling point of a liquid (a solvent) will be higher when another compound is added, meaning that a solution has a higher boiling point than a pure solvent. This happens whenever a non-volatile solute, such as a salt, is added to a pure solvent, such as water. The boiling point can be measured accurately using an ebullioscope. The boiling point elevation is a colligative property, which means that it is dependent on the presence of dissolved particles and their number, but not their identity.
Freezing-point depression is a drop in the maximum temperature at which a substance freezes, caused when a smaller amount of another, non-volatile substance is added. Examples include adding salt into water (used in ice cream makers and for de-icing roads), alcohol in water, ethylene or propylene glycol in water (used in antifreeze in cars), adding copper to molten silver (used to make solder that flows at a lower temperature than the silver pieces being joined), or the mixing of two solids such as impurities into a finely powdered drug.
In thermodynamics, the ebullioscopic constant Kb relates molality b to boiling point elevation. It is the ratio of the latter to the former: i is the van 't Hoff factor, the number of particles the solute splits into or forms when dissolved. b is the molality of the solution. A formula to compute the ebullioscopic constant is: R is the ideal gas constant. Tb is boiling point of the solvent. M is the molar mass of the solvent. ΔHvap is the molar enthalpy of vaporization.
In chemistry, colligative properties are those properties of solutions that depend on the ratio of the number of solute particles to the number of solvent particles in a solution, and not on the nature of the chemical species present.McQuarrie, Donald, et al. Colligative properties of Solutions" General Chemistry Mill Valley: Library of Congress, 2011. . The number ratio can be related to the various units for concentration of a solution such as molarity, molality, normality (chemistry), etc.
Osmosis (ɒzˈmoʊsɪs, ɒs-) is the spontaneous net movement or diffusion of solvent molecules through a selectively-permeable membrane from a region of high water potential (region of lower solute concentration) to a region of low water potential (region of higher solute concentration), in the direction that tends to equalize the solute concentrations on the two sides. It may also be used to describe a physical process in which any solvent moves across a selectively permeable membrane (permeable to the solvent, but not the solute) separating two solutions of different concentrations.
