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This lecture covers various physical vapor deposition (PVD) techniques such as ion plating, molecular beam epitaxy (MBE), and pulsed laser deposition (PLD). It explains the principles behind ion-assisted deposition, epitaxy, and the advantages of MBE and PLD in thin film fabrication. The lecture also delves into the process of Parylene coating, comparing different PVD methods, and discussing film growth and control parameters.