Linked Metal-cluster Systems: Isolation and Characterization of {anti-[(p-cymene)RuCl]-m-[k 2-P,P';k 1-P''-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2
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The molecular forms of LiF, LiFHF and Na2SiF6 have been stabilized using trinuclear metallamacrocyclic complexes of (cymene)Ru-II, (Cp*)Rh-III and (Cp*)Ir-III as specific receptors. The host-guest complexes were characterized by NMR spectroscopy and single ...
The detn. of residual dipolar couplings (RDCs) by quant. J spectroscopy methods such as heteronuclear single quantum correlation with phase encoded coupling (HSQC-PEC) is prone to systematic errors that may be caused by differential attenuation during the ...
The reaction of half-sandwich complexes of ruthenium, rhodium, and iridium with amino-substituted 3-hydroxy-2-pyridone ligands in aqueous solution gives monomeric O,O'-chelate complexes. Upon addition of base, the complexes assemble to form trimeric metall ...
The synthesis and structural properties of three new hydridorhodium(III) complexes are reported. Hydrogenolysis of the cyclometalated Rh dichloride complexes [RhCl2{(S,S)-benbox(Me2)}] (2a-c; benbox(Me2) = 3,5-dimethyl-2,6-bis[(4-R1-4-R2-4,5-dihydrooxazol- ...
The detn. of residual dipolar couplings (RDCs) by quant. J spectroscopy methods such as heteronuclear single quantum correlation with phase encoded coupling (HSQC-PEC) is prone to systematic errors that may be caused by differential attenuation during the ...
We present the design, fabrication and test of high-Q factor radiofrequency planar microcoils for nuclear magnetic resonance (NMR) spectroscopy in small volume samples. The coils are fabricated on glass wafers using high-aspect ratio SU-8 photoepoxy and co ...
NMR spectroscopy is one of the newer spectroscopic techniques for investigating the static, dynamic and electronic structures of molecules adsorbed onto metal catalyst surfaces. We review recent progress in the application of solid-state NMR methods to the ...
The reaction of pyrrole-2,5-dicarbaldehyde (1) with o-phenylenediamine (2) in anhyd. EtOH afforded a [1+1]-condensation product, viz., Schiff's base. The structure of the latter was established by NMR spectroscopy and x-ray diffraction anal. The reaction o ...
Two-dimensional Fourier transform (2D FT) spectroscopy was applied to ion-cyclotron resonance (ICR) to obtain direct evidence for mass transfer due to ion-mol. collisions. The 2D FT ICR expt., which is closely analogous to 2D exchange NMR spectroscopy (NOE ...