Structural, Spectroscopic, and Thermodynamic Consequences of Anti-Chelate Effect in Nine-Coordinate Lanthanide Podates
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We report on seven new anionic benzimidazole-pyridine carboxylate and tetrazolate tridentate (NNO)-N-boolean AND-O-boolean AND and (NNN)-N-boolean AND-N-boolean AND ligands that are modified with chromophore (phenyl, biphenyl, naphthyl) and solubilizing gr ...
Dynamic nuclear polarization surface enhanced NMR (DNP-SENS), Mossbauer spectroscopy, and computational chemistry were combined to obtain structural information on the active-site speciation in Sn-beta zeolite. This approach unambiguously shows the presenc ...
We present here the design of a linear octupole ion trap, suitable for collisional cryogenic cooling and spectroscopy of large ions. The performance of this trap has been assessed using ultraviolet (UV) photofragmentation spectroscopy of protonated dipepti ...
When adsorbing guest molecules, the porous metal-organic framework MIL-53(Cr) may vary its cell parameters drastically while retaining its crystallinity. A first approach to the thermodynamic analysis of this "framework breathing" consists of comparing the ...
A laser spectroscopic study on the structure and dynamics of cold host–guest inclusion complexes of crown ethers (CEs) with various neutral and ionic species in the gas phase is presented. The complexes with neutral guest species are formed by using supers ...
The bis-tetrazolate-pyridine ligand H2pytz sensitises efficiently the visible and/or near-IR luminescence emission of ten lanthanide cations (Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb). The LnIII complexes present sizeable quantum yields in both domains with ...
The activation of highly catalytic gamma-alumina surfaces by thermal treatment and the description of the related chemical processes at atomic scale is a topical issue. According to a recent study [J. Am. Chem. Soc. 134 (2012) 14430], the enhanced reactivi ...
The Second Law of thermodynamics is known to be an essential guide for the improvement of energy conversion systems. Throughout the years it has been applied to various engineering methods in particular in methods based on exergy [1] including the 2nd Law, ...
Emission spectroscopy measurements on a plasma representative of Titan atmosphere composition were obtained in the Inductively Coupled Plasma wind tunnel facility (VKI-Minitorch) at the von Karman Institute in Belgium. Temperatures ranged from 3600 to 5000 ...
We perform quantum mechanics/molecular mechanics molecular dynamics simulations on the Pt-2(P2O5H2)(4) (abbreviated PtPOP) complex; in water, dimethylformamide and ethanol. These are used to calculate the ground state X-ray absorption spectrum of the ...