Structural, Spectroscopic, and Thermodynamic Consequences of Anti-Chelate Effect in Nine-Coordinate Lanthanide Podates
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The three-dimensional (3D) structures of proteins and peptides in vivo largely determine their biological functions. In vitro these native structures and their heterogeneity reflect a subtle balance between noncovalent intramolecular interactions and those ...
The enantiomerically pure pinene-bipyridine-based receptor, (-) or (+) L-, diastereoselectively self-assembles in dry acetonitrile in the presence of Ln(III) ions (Ln = La, Pr, Nd, Sm, Eu, Gd, and Tb) to give a C-3-symmetrical, pyramidal architecture with ...
A new class of benzimidazole-substituted 8-hydroxyquinoline ligands has been prepared that contain a monoanionic tridentate N,N,O-coordinating unit. These ligands form charge-neutral lanthanide complexes of the type [Ln(LR) 3] · nH2O or [Ln2(L2)3] · nH2O ( ...
Basic thermodynamic considerations are used to rationalize the formation of thermotropic mesophases incorporating aromatic ligands for trivalent lanthanide metal ions (Ln). Standard flat and bent molecular interfaces, separating the central binding unit fr ...
Network models have been used to study the underlying processes and principles of biological systems for decades, providing many insights into the complexity of life. Biological systems require a constant flow of free energy to drive these processes that o ...
The magnetic entropy variation for the ordered spin-ice Tb2Sn2O7 and the spin-liquid Tb2Ti2O7 measured up to similar to 20 K shows that the crystal-field ground state for both systems is a singlet split from the first excited level by a thermal energy of s ...
The temperature behavior of the generation of the second acoustic harmonics induced by an electric field during the transition of a crystal to the ferroelectric state has been considered based on the thermodynamic approach in the framework of the Landau mo ...
Dimethylaminonitrene complexes of IMesM+ (IMes = 1,3-bis(2,4,6-trimethylphenyl)- imidazol-2-ylidene; M = Cu, Ag, Au) were prepared in the gas phase and structurally characterized by high-resolution infrared spectroscopy of the cold species, ion-molecule re ...
One- and two-photon excitation spectra of sodium atoms on the surface of helium droplets are reported. The spectra are recorded by monitoring the photoionization yield of desorbed atoms as function of excitation frequency. The excitation spectra involving ...