Dynamics of Electron Transfer Processes at the Surface of Dye-Sensitized Mesoporous Semiconductor Films
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Photoinduced electron transfer from organic dye molecules to semiconductor nanoparticles is the first and most important reaction step for the mechanism in the so called “wet solar cells” [1]. The time scale between the photoexcitation of the dye and the e ...
Due to their high efficiencies and their potentially low production costs, dye-sensitized solar cells (DSSC) have attracted much attention during the last few years. The technology is based on a layer made of mesoscopic TiO2 film which significantly increa ...
This thesis presents a new type of photovoltaic solar cell based on dye-sensitized nanocrystalline titanium dioxide electrodes. In contrast to conventional solar cells, where light absorption is due to band gap excitation of the semiconductor itself, TiO2 ...
The electron transport in dye-sensitized solar cells with a MOCVD (metal org. vapor deposition)-grown ZnO nanorod array (ZnO-N) or a mesoporous film prepd. from ZnO colloids (ZnO-C) as the working electrode was compared. The electrodes were of similar thic ...
Influence of processing parameters, such as autoclaving and firing temp., on the optical properties of nanocryst. anatase TiO2 film and on the process of electron injection from the dye fluorescein 27 to the as-prepd. films is studied. TEM and steady-state ...
The dynamics of electron-transfer processes between bis(tetrabutylammonium) cis-bis(thiocyanato)bis(2,2'-bipiridine-4,4'-dicarboxylato)ruthenium(II) (called N719) and nanostructured ZnO films were studied by femtosecond and nanosecond spectroscopy. The inc ...
The effect of electronic and nuclear factors on the dynamics of dye-to-semiconductor electron transfer was studied employing RuII(terpy)(NCS)3 sensitizers grafted onto transparent films made of titanium dioxide nanoparticles. Various approaches were strive ...
Accelerated bleaching and photobleaching of diluted solutions of Methyl Orange and other dyes occur only when Co2+-ions are present in solution mediating oxone (2KHSO(5)center dot KHSO4 center dot K2SO4) decomposition. The bleaching of Methyl Orange, Orang ...
Transient and spectral photovoltage (PV) have been investigated for charge injection from a dye [Ru(dcbpyH2)2(NCS)2] into transparent hole (CuSCN, CuI, CuAlO2) and electron ( TiO2, SnO2:F) conductors. The PV signal rises to a max. within 10 ns to 10 μs, de ...
The electron transfer (ET) from organic dye molecules to semiconductor-colloidal systems is characterized by a special energetic situation with a charge transfer reaction from a system of discrete donor levels to a continuum of acceptor states. If these sy ...