Experimental determination of the oscillator strength of the 2160 A band of the free methyl radical and a spectroscopic measurement of the combination rate

Hubert van den Bergh
1969
Journal paper

Abstract

The f-value of the 2160-.ANG. band of the free Me radical was detd. exptl. as (1.2 +- 0.2) * 10-2. The rate coeff. for combination is (2.43 +- 0.24) * 1013 cm3/mole-sec at 293 DegK. Me radicals were generated by the flash photolysis of small partial pressures of both Me2Hg and azomethane with Ar added to 100 torr in all expts.

Official source

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Experimental determination of the oscillator strength of the 2160 A band of the free methyl radical and a spectroscopic measurement of the combination rate

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