Radical (chemistry)In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes. A notable example of a radical is the hydroxyl radical (HO·), a molecule that has one unpaired electron on the oxygen atom. Two other examples are triplet oxygen and triplet carbene (꞉CH2) which have two unpaired electrons.
Chandrasekhar limitThe Chandrasekhar limit (tʃʌndrəˈseɪkər) is the maximum mass of a stable white dwarf star. The currently accepted value of the Chandrasekhar limit is about (2.765e30kg). White dwarfs resist gravitational collapse primarily through electron degeneracy pressure, compared to main sequence stars, which resist collapse through thermal pressure. The Chandrasekhar limit is the mass above which electron degeneracy pressure in the star's core is insufficient to balance the star's own gravitational self-attraction.
Electron degeneracy pressureIn astrophysics and condensed matter, electron degeneracy pressure is a quantum mechanical effect critical to understanding the stability of white dwarf stars and metal solids. It is a manifestation of the more general phenomenon of quantum degeneracy pressure. In metals and white dwarf stars, electrons can be modeled as a gas of non-interacting electrons confined to a finite volume. In reality, there are strong electromagnetic forces between the negatively charged electrons.
Methyl groupIn organic chemistry, a methyl group is an alkyl derived from methane, containing one carbon atom bonded to three hydrogen atoms, having chemical formula . In formulas, the group is often abbreviated as Me. This hydrocarbon group occurs in many organic compounds. It is a very stable group in most molecules. While the methyl group is usually part of a larger molecule, bounded to the rest of the molecule by a single covalent bond (), it can be found on its own in any of three forms: methanide anion (), methylium cation () or methyl radical (CH3•).
Radical initiatorIn chemistry, radical initiators are substances that can produce radical species under mild conditions and promote radical reactions. These substances generally possess weak bonds—bonds that have small bond dissociation energies. Radical initiators are utilized in industrial processes such as polymer synthesis. Typical examples are molecules with a nitrogen-halogen bond, azo compounds, and organic and inorganic peroxides. Halogens undergo homolytic fission relatively easily.
