Publication

Covalent Capture of Nitrous Oxide by N-Heterocyclic Carbenes

Rosario Scopelliti, Kay Severin, Matthew Wodrich, Euro Solari, Alexander Tskhovrebov
2012
Journal paper

Abstract

A good catch: N-heterocyclic carbenes (NHCs) form stable adducts with nitrous oxide (N2O) under mild reaction conditions. The adducts display unique reactivity as evidenced by an alkylation reaction which leads to a rupture of the NN bond.

Official source

https://infoscience.epfl.ch/record/170266?ln=en

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Covalent Capture of Nitrous Oxide by N-Heterocyclic Carbenes

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Isolation, Characterisation and Reactivity of N-Heterocyclic Diazoolefins

Synthetic chemistry with nitrous oxide and triazenes

SET processes in Lewis acid–base reactions: the tritylation of N-heterocyclic carbenes

Isolation, Characterisation and Reactivity of N-Heterocyclic Diazoolefins

Synthetic chemistry with nitrous oxide and triazenes

SET processes in Lewis acid–base reactions: the tritylation of N-heterocyclic carbenes