Perturbation theoryIn mathematics and applied mathematics, perturbation theory comprises methods for finding an approximate solution to a problem, by starting from the exact solution of a related, simpler problem. A critical feature of the technique is a middle step that breaks the problem into "solvable" and "perturbative" parts. In perturbation theory, the solution is expressed as a power series in a small parameter . The first term is the known solution to the solvable problem. Successive terms in the series at higher powers of usually become smaller.
Radial velocityThe radial velocity or line-of-sight velocity, also known as radial speed or range rate, of a target with respect to an observer is the rate of change of the distance or range between the two points. It is equivalent to the vector projection of the target-observer relative velocity onto the relative direction connecting the two points. In astronomy, the point is usually taken to be the observer on Earth, so the radial velocity then denotes the speed with which the object moves away from the Earth (or approaches it, for a negative radial velocity).
Perturbation theory (quantum mechanics)In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation for describing a complicated quantum system in terms of a simpler one. The idea is to start with a simple system for which a mathematical solution is known, and add an additional "perturbing" Hamiltonian representing a weak disturbance to the system. If the disturbance is not too large, the various physical quantities associated with the perturbed system (e.g.
Doppler spectroscopyDoppler spectroscopy (also known as the radial-velocity method, or colloquially, the wobble method) is an indirect method for finding extrasolar planets and brown dwarfs from radial-velocity measurements via observation of Doppler shifts in the spectrum of the planet's parent star. As of November 2022, about 19.5% of known extrasolar planets (1,018 of the total) have been discovered using Doppler spectroscopy. Otto Struve proposed in 1952 the use of powerful spectrographs to detect distant planets.
Supercritical fluidA supercritical fluid (SCF) is any substance at a temperature and pressure above its critical point, where distinct liquid and gas phases do not exist, but below the pressure required to compress it into a solid. It can effuse through porous solids like a gas, overcoming the mass transfer limitations that slow liquid transport through such materials. SCF are much superior to gases in their ability to dissolve materials like liquids or solids.
Supercritical carbon dioxideSupercritical carbon dioxide (sCO2) is a fluid state of carbon dioxide where it is held at or above its critical temperature and critical pressure. Carbon dioxide usually behaves as a gas in air at standard temperature and pressure (STP), or as a solid called dry ice when cooled and/or pressurised sufficiently. If the temperature and pressure are both increased from STP to be at or above the critical point for carbon dioxide, it can adopt properties midway between a gas and a liquid.
Prompt criticalityIn nuclear engineering, prompt criticality describes a nuclear fission event in which criticality (the threshold for an exponentially growing nuclear fission chain reaction) is achieved with prompt neutrons alone and does not rely on delayed neutrons. As a result, prompt supercriticality causes a much more rapid growth in the rate of energy release than other forms of criticality. Nuclear weapons are based on prompt criticality, while nuclear reactors rely on delayed neutrons or external neutrons to achieve criticality.
Supercritical fluid extractionSupercritical fluid extraction (SFE) is the process of separating one component (the extractant) from another (the matrix) using supercritical fluids as the extracting solvent. Extraction is usually from a solid matrix, but can also be from liquids. SFE can be used as a sample preparation step for analytical purposes, or on a larger scale to either strip unwanted material from a product (e.g. decaffeination) or collect a desired product (e.g. essential oils). These essential oils can include limonene and other straight solvents.
Critical massIn nuclear engineering, a critical mass is the smallest amount of fissile material needed for a sustained nuclear chain reaction. The critical mass of a fissionable material depends upon its nuclear properties (specifically, its nuclear fission cross-section), density, shape, enrichment, purity, temperature, and surroundings. The concept is important in nuclear weapon design. When a nuclear chain reaction in a mass of fissile material is self-sustaining, the mass is said to be in a critical state in which there is no increase or decrease in power, temperature, or neutron population.
Nuclear chain reactionIn nuclear physics, a nuclear chain reaction occurs when one single nuclear reaction causes an average of one or more subsequent nuclear reactions, thus leading to the possibility of a self-propagating series of these reactions. The specific nuclear reaction may be the fission of heavy isotopes (e.g., uranium-235, 235U). A nuclear chain reaction releases several million times more energy per reaction than any chemical reaction.
