Photoinduced Biphasic Hydrogen Evolution: Decamethylosmocene as a Light-Driven Electron Donor
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In water, spin–lattice relaxation times (T1) and calibration curves for chemical shifts have been determined for the 13C and the 1H (C) atoms in HCOOH, HCOONa, CO2, Na2CO3 and NaHCO3 by NMR spectroscopy. These data facilitate kinetic and mechanistic studie ...
Molecular hydrogen is a promising candidate to replace fossil fuels as the energy carrier. Hydrogen does not exist in its molecular form on earth and must therefore be generated, starting from hydrogen-rich compounds. Water would be a renewable resource fo ...
Comprehensive studies of gas-solid reactions require the in-situ interaction of the gas at a pressure beyond the operating pressure of ultrahigh vacuum (UHV) X-ray photoelectron spectroscopy (XPS). The recent progress of near ambient pressure XPS allows to ...
The progressive integration of renewable energy sources such as wind turbines and photovoltaic pannels in the current electrical network, and the rise of the electrical mobility, provoke a change of paradigm in the sector of energy management. The increasi ...
A major challenge in the face of increasing global energy demand is the development of alternative environmentally friendly and renewable energy resources. Hydrogen is an excellent energy carrier, but has drawbacks in storage density and is dangerous to ha ...
Y(BH4)3 is one of the candidates for solid-state hydrogen storage, which contains 9.06 wt% of hydrogen. In this study, the thermal properties of Y(BH4)3 synthesized via two different methods are extensively examined. One method relies on the solid-solid me ...
Solvents play a crucial role in many chemical reactions and additives can be used to shift the reaction equilibrium. Herein we study the enthalpy of mixing for selected solvents (aqueous, organic) and basic additives (amines, aqueous KOH) when mixed with f ...
The synthesis of a new series of neutral bis[2-(2,4-difluorophen-2-yl)pyridine][1-(2-aryl)-3-methylimidazol-2-ylidene]iridium(III) complexes is reported. Each complex has been characterized by NMR spectroscopy, UV/Vis spectrophotometry, and cyclic voltamme ...
The goal of this rapport is to present an overview of the different hydrogen storage technologies, currently available for industrial application or at earlier stages of development. In order to identify the water and mechanical work requirements for compr ...
Natural attenuation of anaerobic aquifers contaminated with tetrachloroethene (PCE) often results in the accumulation of the intermediates cis-dichloroethene and vinyl chloride (VC) which are even more toxic than the parent compound. Reasons for this accum ...