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(Arene)ruthenium Complexes with Imidazolin-2-imine and Imidazolidin-2-imine Ligands

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Enantioselective C-H Bond Functionalizations by 3d Transition-Metal Catalysts

Nicolai Cramer

Direct catalytic modifications of carbon-hydrogen (C-H) bonds, ubiquitous in organic molecules, represent a powerful strategy in organic synthesis. In the past decade, chemists have focused on the development of sustainable methods for functionalization of ...

ELSEVIER2019

Des bactéries pour soutenir le sol de Rances

Rances in the north of Vaud suffered last year from the effects of large soil movement. Rances became the new playground where MeduSoil technology was tested as a remediation for this type of events. This is a decisive new step, after the technology has be ...

2018

Des bactéries contre l'érosion

2018

A Monometallic Iron(I) Organoferrate

Xile Hu, Matthew Wodrich, Fedor Zhurkin

Tetra-n-butylammonium (TBA) (eta(6)-biphenyl)diphenyfferrate was formed unexpectedly in the reaction of (TBA)(2)[Fe4S4Cl4] with an excess of phenyllithium. This complex belongs to a novel type of organoferrate. ...

American Chemical Society2017

Robust Type-II Weyl Semimetal Phase in Transition Metal Diphosphides XP2 (X = Mo, W)

Oleg Yazyev, Gabriel Albert Autes

The recently discovered type-II Weyl points appear at the boundary between electron and hole pockets. Type-II Weyl semimetals that host such points are predicted to exhibit a new type of chiral anomaly and possess thermodynamic properties very different fr ...

Amer Physical Soc2016

Fe N-Heterocyclic Carbene Complexes as Promising Photosensitizers

Yizhu Liu

The photophysics and photochemistry of transition metal complexes (TMCs) has long been a hot field of interdisciplinary research. Rich metal-based redox processes, together with a high variety in electronic configurations and excited-state dynamics, have r ...

Amer Chemical Soc2016

Effects as Implicit Capabilities

Martin Odersky

We propose to investigate a new approach to effect checking that has an elegant solution to the effect polymorphism problem. The central idea is that instead of talking about effects we talk about capabilities. For instance, instead of saying a function “t ...

2015

Chiral Cyclopentadienyl Iridium(III) Complexes Promote Enantioselective Cycloisomerizations Giving Fused Cyclopropanes

Nicolai Cramer, Yun-Suk Jang, Michael Christian Dieckmann

The cyclopentadienyl (Cp) group is a very important ligand for many transition-metal complexes which have been applied in catalysis. The availability of chiral cyclopentadienyl ligands (Cp-x) lags behind other ligand classes, thus hampering the investigati ...

Wiley-V C H Verlag Gmbh2015

On type I blow up formation for the critical NLW

Joachim Krieger, Willie Wai Yeung Wong

We introduce a suitable concept of weak evolution in the context of the radial quintic focussing semilinear wave equation on R^{3+1}, that is adapted to continuation past type II singularities. We show that the weak extension leads to type I singularity fo ...

Taylor & Francis2014

Méthode de libération d'une pièce micromécanique et pièce micromécanique comprenant des attaches sacrificielles

Simon Nessim Henein, François Barrot, Johannes Richard Cornelis Geerit Kruis, Rémy Fournier

A method for fabricating a micromechanical part from a substrate in which the part is fabricated by providing a plurality of fasteners between the part and the substrate, the fasteners being sacrificial, characterized in that the fasteners include at least ...

Organisation Mondiale de la Propriété Intellectuelle2013