The 2D MAS NMR spin-echo experiment: the determination of C-13-C-13 J couplings in a solid-state cellulose sample
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Fractionation of isotopes among distinct molecules or phases is a quantum effect which is often exploited to obtain insights on reaction mechanisms, biochemical, geochemical, and atmospheric phenomena. Accurate evaluation of isotope ratios in atomistic sim ...
The net benefit of agroforestry trees for small scale farmers in dryland agricultural systems is debatable because while they provide significant direct and indirect services, they also consume considerable amounts of scare water resources. In this study w ...
A method to label marine biocarbonates is developed based on a concentration enrichment of a minor stable isotope of a trace element that is a natural component of seawater, resulting in the formation of biocarbonate with corresponding isotopic enrichments ...
Ureilites are ultramafic achondrites formed by igneous processes early in the history of the Solar System. Ureilites are heavily depleted in volatile elements, probably by evaporation at the surface of the ureilite parent body: however the moderately volat ...
The application of stable Fe isotopes as a tracer of the biogeochemical Fe cycle necessitates a mechanistic knowledge of natural fractionation processes. We studied the equilibrium Fe isotope fractionation upon sorption of Fe(II) to aluminum oxide (gamma-A ...
Mass transfer of organic contaminants from nonaqueous phase liquids to the aqueous phase can significantly modulate the observable carbon isotope fractionation behavior associated with contaminant transformation. We evaluated the effects of kinetic interph ...
Using the CRPG-CNRS Cameca 1270 ion microprobe facility, we have measured boron isotopic compositions (B-11/B-10) in different ultrastructural components of the deep-sea aragonitic scleractinian coral Lophelia pertusa. We observe a systematic difference in ...
We recently demonstrated an original approach to highly selective laser isotope separation of carbon-13 that employs vibrational overtone pre-excitation of CF3 H together with infrared multiphoton dissociation [O.V. Boyarkin, M. Kowalczyk, T.R. Rizzo, J. C ...
In this paper we present two compact, quantum cascade laser absorption spectroscopy based, sensors developed for trace substance detection in gases and liquids. The gas sensor, in its most integrated version, represents the first system combining a quantum ...
Iron isotopes were used to investigate iron transformation processes during an in situ field experiment for removal of dissolved Fe from reduced groundwater. This experiment provided a unique setting for exploring Fe isotope fractionation in a natural syst ...