Reference materials for stable isotope analysisIsotopic reference materials are compounds (solids, liquids, gasses) with well-defined isotopic compositions and are the ultimate sources of accuracy in mass spectrometric measurements of isotope ratios. Isotopic references are used because mass spectrometers are highly fractionating. As a result, the isotopic ratio that the instrument measures can be very different from that in the sample's measurement. Moreover, the degree of instrument fractionation changes during measurement, often on a timescale shorter than the measurement's duration, and can depend on the characteristics of the sample itself.
Isotopic signatureAn isotopic signature (also isotopic fingerprint) is a ratio of non-radiogenic 'stable isotopes', stable radiogenic isotopes, or unstable radioactive isotopes of particular elements in an investigated material. The ratios of isotopes in a sample material are measured by isotope-ratio mass spectrometry against an isotopic reference material. This process is called isotope analysis. The atomic mass of different isotopes affect their chemical kinetic behavior, leading to natural isotope separation processes.
Isotope analysisIsotope analysis is the identification of isotopic signature, abundance of certain stable isotopes of chemical elements within organic and inorganic compounds. Isotopic analysis can be used to understand the flow of energy through a food web, to reconstruct past environmental and climatic conditions, to investigate human and animal diets, for food authentification, and a variety of other physical, geological, palaeontological and chemical processes.
Formation and evolution of the Solar SystemThe formation of the Solar System began about 4.6 billion years ago with the gravitational collapse of a small part of a giant molecular cloud. Most of the collapsing mass collected in the center, forming the Sun, while the rest flattened into a protoplanetary disk out of which the planets, moons, asteroids, and other small Solar System bodies formed. This model, known as the nebular hypothesis, was first developed in the 18th century by Emanuel Swedenborg, Immanuel Kant, and Pierre-Simon Laplace.
Planetary coreA planetary core consists of the innermost layers of a planet. Cores may be entirely solid or entirely liquid, or a mixture of solid and liquid layers as is the case in the Earth. In the Solar System, core sizes range from about 20% (the Moon) to 85% of a planet's radius (Mercury). Gas giants also have cores, though the composition of these are still a matter of debate and range in possible composition from traditional stony/iron, to ice or to fluid metallic hydrogen.
Planetary differentiationIn planetary science, planetary differentiation is the process by which the chemical elements of a planetary body accumulate in different areas of that body, due to their physical or chemical behavior (e.g. density and chemical affinities). The process of planetary differentiation is mediated by partial melting with heat from radioactive isotope decay and planetary accretion. Planetary differentiation has occurred on planets, dwarf planets, the asteroid 4 Vesta, and natural satellites (such as the Moon).
Isotope geochemistryIsotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various elements. Variations in isotopic abundance are measured by isotope ratio mass spectrometry, and can reveal information about the ages and origins of rock, air or water bodies, or processes of mixing between them. Stable isotope geochemistry is largely concerned with isotopic variations arising from mass-dependent isotope fractionation, whereas radiogenic isotope geochemistry is concerned with the products of natural radioactivity.
Isotopic labelingIsotopic labeling (or isotopic labelling) is a technique used to track the passage of an isotope (an atom with a detectable variation in neutron count) through a reaction, metabolic pathway, or cell. The reactant is 'labeled' by replacing specific atoms by their isotope. The reactant is then allowed to undergo the reaction. The position of the isotopes in the products is measured to determine the sequence the isotopic atom followed in the reaction or the cell's metabolic pathway.
Solar SystemThe Solar System is the gravitationally bound system of the Sun and the objects that orbit it. The largest of such objects are the eight planets, in order from the Sun: four terrestrial planets named Mercury, Venus, Earth and Mars, two gas giants named Jupiter and Saturn, and two ice giants named Uranus and Neptune. The terrestrial planets have a definite surface and are mostly made of rock and metal. The gas giants are mostly made of hydrogen and helium, while the ice giants are mostly made of 'volatile' substances such as water, ammonia, and methane.
GeochemistryGeochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the entire Solar System, and has made important contributions to the understanding of a number of processes including mantle convection, the formation of planets and the origins of granite and basalt. It is an integrated field of chemistry and geology.
