Publications related to Hydrogen Dynamics in Nanoconfined Lithiumborohydride

Amorphous Molybdenum Sulfide Films as Hydrogen Evolution Catalysts in Water

Molecular hydrogen is a promising candidate to replace fossil fuels as the energy carrier. Hydrogen does not exist in its molecular form on earth and must therefore be generated, starting from hydrogen-rich compounds. Water would be a renewable resource fo ...

EPFL2012

Mobility and dynamics in the complex hydrides LiAlH4 and LiBH4

Pascal Martelli

The dynamics and bonding of the complex hydrides LiBH4 and LiAlH4 have been investigated by vibrational spectroscopy. The combination of infrared, Raman, and inelastic neutron scattering (INS) spectroscopies on hydrided and deuterided samples reveals a com ...

2011

Artificial Photosynthesis at Soft Interfaces

Hubert Girault, Fernando Cortes Salazar, Manuel Alejandro Méndez Agudelo, Peiyu Ge, Haiqiang Deng, Imren Hatay, Patrick Voyame, Zahra Nazemi

The concept of artificial photosynthesis at a polarised liquid membrane is presented. It includes two photosystems, one at each interface for the hydrogen and oxygen evolution respectively. Both reactions involve proton coupled electron transfer reactions, ...

Schweizerische Chemische Gesellschaft2011

A multifaceted approach to hydrogen storage

Bengt Kasemo

The widespread adoption of hydrogen as an energy carrier could bring significant benefits, but only if a number of currently intractable problems can be overcome. Not the least of these is the problem of storage, particularly when aimed at use onboard ligh ...

2011

Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media

Hubert Girault, Manuel Alejandro Méndez Agudelo, Bin Su, Peiyu Ge, Imren Hatay, Zdenek Samec

Experimental studies and density functional theory (DFT) computations suggest that oxygen and proton reduction by decamethylferrocene (DMFc) in 1,2-dichloroethane involves protonated DMFc, DMFcH+, as an active intermediate species, producing hydrogen perox ...

Royal Society of Chemistry2010

Effect of additives on the synthesis and reversibility of Ca(BH4)(2)

Metal borohydrides are potential materials for solid-state hydrogen due to their high gravimetric and volumetric hydrogen densities. Among them, Ca(BH4)2 is particularly interesting because of the predicted suitable thermodynamic properties. In this work, ...

2010

BH4- Self-Diffusion in Liquid LiBH4

Philippe Mauron, Pascal Martelli

The hydrogen dynamics in solid and in liquid LiBH4 was studied by means of incoherent quasielastic neutron scattering. Rotational jump diffusion of the BH4 - subunits on the picosecond scale was observed in solid LiBH4. The characteristic time constant is ...

2010

Dynamics and Thermodynamics of a Novel Phase of NaAlH4

Nicola Marzari

We characterize a novel orthorhombic phase (gamma) of NaAlH4, discovered using first-principles molecular dynamics, and discuss its relevance to the dehydrogenation mechanism. This phase is close in energy to the known low-temperature structure and becomes ...

2009

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring

Albert Renken, Lioubov Kiwi, Martin Grasemann

Systematic studies of mass transfer interactions with intrinsic reaction kinetics were performed for the threephase selective hydrogenation of 2-methyl-3-butyn-2-ol (MBY) to 2-methyl-3-buten-2-ol (MBE) over a modified Pd/CaC

{O}_{3}

catalyst under solvent ...

2008

Electrocatalytic hydrogen evolution at positive potentials

Xile Hu

Hydrogen prodn. using earth abundant metals is one of the important challenges facing an energy economy based upon solar fuels. Schemes that incorporate the photo-oxidn. of water must also include schemes for efficiently converting released protons and ele ...

2007

Hydrogen Dynamics in Nanoconfined Lithiumborohydride

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Amorphous Molybdenum Sulfide Films as Hydrogen Evolution Catalysts in Water

Mobility and dynamics in the complex hydrides LiAlH4 and LiBH4

Artificial Photosynthesis at Soft Interfaces

A multifaceted approach to hydrogen storage

Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media

Effect of additives on the synthesis and reversibility of Ca(BH4)(2)

BH4- Self-Diffusion in Liquid LiBH4

Dynamics and Thermodynamics of a Novel Phase of NaAlH4

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring

Electrocatalytic hydrogen evolution at positive potentials

Amorphous Molybdenum Sulfide Films as Hydrogen Evolution Catalysts in Water

A multifaceted approach to hydrogen storage

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring

Electrocatalytic hydrogen evolution at positive potentials

Artificial Photosynthesis at Soft Interfaces

Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media

Effect of additives on the synthesis and reversibility of Ca(BH4)(2)

Dynamics and Thermodynamics of a Novel Phase of NaAlH4

BH4- Self-Diffusion in Liquid LiBH4

Mobility and dynamics in the complex hydrides LiAlH4 and LiBH4