Intrachain antiferromagnetic exchange in a 1D branched-chain built of two different copper(II) centres interlinked by end-on azido and phenoxo bridges: electron density map, electrochemical and magnetic properties
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Metal Complexes of Biologically Important Ligands, LXX[1].- Synthesis, Stereochemistry and Reactions of Ruthenium(II) and Osmium(II) Complexes with -Amino Carboxylates. The reactions of MHCl(CO)(PPh3)3 with salts of -amino acids give the hydrido-N,O-chelat ...
The indium desorption rates from InGaAs and InAlAs grown on InP substrates have been measured by wedge transmission electron microscopy as a function of the growth temperature. Desorption becomes significant at 545-degrees-C for both materials. No automatc ...
The thermal reaction Of Ru3(CO)12 with (+/-) 7-oxabicyclo[2.2.1]hept-5-en-2-one (+/-)-2, (+/-) 7-oxabicyclo[2.2.1]hept-5-en-2-endo-ol 21 and the corresponding benzoate 22 afforded the [Ru3H2(CO)9 (7-oxabicyclo[2.2.1]hept-5-yn-2-yl)] clusters 13, 19 and 20, ...
The electronic structures of different phosphates were studied by using the DV-X alpha cluster molecular orbital method, Experimental data on crystal structures from x-ray diffraction measurements were used to set up realistic model clusters. Theoretical X ...
Large errors may occur in the X-ray diffraction determination of epitaxial layer mismatch, thicknesses or/and periodicity if the substrate miscut angle is not taken into account. Misoriented sample rocking curves are indeed strongly affected when the azimu ...
The reactions of [Fe2(CO)9] with 2-exo,3-exo-bis(chloromethyl)-5,6-di(methylidene)-7-oxabicyclo[2.2.1]hep tane (5) and with 5,6-di(methylidene)-7-oxabicyclo[2.2.1]heptane-2-exo,3-exo-dimethyl bis(methanesulfonate) (6) afforded, together with the correspond ...
The structures of the cubic, the tetragonal and the orthorhombic phases of single crystals of the ferroelectric aluminate sodalite Sr/sub 8/(Al/sub 12/O/sub 24/)(CrO/sub 4/)/sub 2/ were investigated by selected area and convergent beam electron diffraction ...
The crystal and molecular structure of dinitrato(1,7,10,16‐tetraoxa‐4,13‐diazacyclooctadecane)europium(III) nitrate, ([Eu(NO3)2(C12H26N2O4)]NO3) has been determined from single‐crystal X‐ ray diffraction: a = 12.567(3), b = 11.585(3), c = 16.354(5) Å, β = ...