Intrachain antiferromagnetic exchange in a 1D branched-chain built of two different copper(II) centres interlinked by end-on azido and phenoxo bridges: electron density map, electrochemical and magnetic properties
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The reactions of [Fe2(CO)9] with 2-exo,3-exo-bis(chloromethyl)-5,6-di(methylidene)-7-oxabicyclo[2.2.1]hep tane (5) and with 5,6-di(methylidene)-7-oxabicyclo[2.2.1]heptane-2-exo,3-exo-dimethyl bis(methanesulfonate) (6) afforded, together with the correspond ...
Metal Complexes of Biologically Important Ligands, LXX[1].- Synthesis, Stereochemistry and Reactions of Ruthenium(II) and Osmium(II) Complexes with -Amino Carboxylates. The reactions of MHCl(CO)(PPh3)3 with salts of -amino acids give the hydrido-N,O-chelat ...
The thermal reaction Of Ru3(CO)12 with (+/-) 7-oxabicyclo[2.2.1]hept-5-en-2-one (+/-)-2, (+/-) 7-oxabicyclo[2.2.1]hept-5-en-2-endo-ol 21 and the corresponding benzoate 22 afforded the [Ru3H2(CO)9 (7-oxabicyclo[2.2.1]hept-5-yn-2-yl)] clusters 13, 19 and 20, ...
The structures of the cubic, the tetragonal and the orthorhombic phases of single crystals of the ferroelectric aluminate sodalite Sr/sub 8/(Al/sub 12/O/sub 24/)(CrO/sub 4/)/sub 2/ were investigated by selected area and convergent beam electron diffraction ...
The indium desorption rates from InGaAs and InAlAs grown on InP substrates have been measured by wedge transmission electron microscopy as a function of the growth temperature. Desorption becomes significant at 545-degrees-C for both materials. No automatc ...
Large errors may occur in the X-ray diffraction determination of epitaxial layer mismatch, thicknesses or/and periodicity if the substrate miscut angle is not taken into account. Misoriented sample rocking curves are indeed strongly affected when the azimu ...
The crystal and molecular structure of dinitrato(1,7,10,16‐tetraoxa‐4,13‐diazacyclooctadecane)europium(III) nitrate, ([Eu(NO3)2(C12H26N2O4)]NO3) has been determined from single‐crystal X‐ ray diffraction: a = 12.567(3), b = 11.585(3), c = 16.354(5) Å, β = ...
The electronic structures of different phosphates were studied by using the DV-X alpha cluster molecular orbital method, Experimental data on crystal structures from x-ray diffraction measurements were used to set up realistic model clusters. Theoretical X ...