Heterogeneous gold catalysisHeterogeneous gold catalysis refers to the use of elemental gold as a heterogeneous catalyst. As in most heterogeneous catalysis, the metal is typically supported on metal oxide. Furthermore, as seen in other heterogeneous catalysts, activity increases with a decreasing diameter of supported gold clusters. Several industrially relevant processes are also observed such as H2 activation, Water-gas shift reaction, and hydrogenation. No gold-catalyzed reaction has been commercialized.
Constrained optimizationIn mathematical optimization, constrained optimization (in some contexts called constraint optimization) is the process of optimizing an objective function with respect to some variables in the presence of constraints on those variables. The objective function is either a cost function or energy function, which is to be minimized, or a reward function or utility function, which is to be maximized.
Sulfide (organic)In organic chemistry, an organic sulfide (British English sulphide) or thioether is an organosulfur functional group with the connectivity as shown on right. Like many other sulfur-containing compounds, volatile sulfides have foul odors. A sulfide is similar to an ether except that it contains a sulfur atom in place of the oxygen. The grouping of oxygen and sulfur in the periodic table suggests that the chemical properties of ethers and sulfides are somewhat similar, though the extent to which this is true in practice varies depending on the application.
Linear acetylenic carbonLinear acetylenic carbon (LAC), also known as carbyne or Linear Carbon Chain (LCC), is an allotrope of carbon that has the chemical structure as a repeat unit, with alternating single and triple bonds. It would thus be the ultimate member of the polyyne family. This polymeric carbyne is of considerable interest to nanotechnology as its Young's modulus is 32.7TPa – forty times that of diamond; this extraordinary number is, however, based on a novel definition of cross-sectional area that does not correspond to the space occupied by the structure.
Standard atmosphere (unit)The standard atmosphere (symbol: atm) is a unit of pressure defined as 101325 Pa. It is sometimes used as a reference pressure or standard pressure. It is approximately equal to Earth's average atmospheric pressure at sea level. The standard atmosphere was originally defined as the pressure exerted by a 760 mm column of mercury at and standard gravity (gn = 9.80665m/s2). It was used as a reference condition for physical and chemical properties, and was implicit in the definition of the Celsius temperature scale, which defined as the boiling point of water at this pressure.
International Standard AtmosphereThe International Standard Atmosphere (ISA) is a static atmospheric model of how the pressure, temperature, density, and viscosity of the Earth's atmosphere change over a wide range of altitudes or elevations. It has been established to provide a common reference for temperature and pressure and consists of tables of values at various altitudes, plus some formulas by which those values were derived. The International Organization for Standardization (ISO) publishes the ISA as an international standard, ISO 2533:1975.
