Publication

Highly efficient perovskite solar cells with a compositionally engineered perovskite​/hole transporting material interface

Abstract

Perovskite solar cells (PSCs) have experienced an outstanding advance in power conversion efficiency (PCE) by optimizing the perovskite layer morphol., compn., interfaces, and charge collection efficiency. To enhance PCE, here we developed a new method i.e., engineering a compositional gradient thinly at the rear interface between the perovskite and the hole transporting materials. We demonstrate that charge collection is improved and charge recombination is reduced by formation of an engineered passivating layer, which leads to a striking enhancement in open-​circuit voltage (VOC)​. The passivation effect induced by constructing an addnl. FAPbBr3-​xIx layer on top of the primary (FAPbI3)​0.85(MAPbBr3)​0.15 film was proven to function as an electron blocking layer within the perovskite film, resulting in a final PCE of 21.3​%. Our results shed light on the importance of the interfacial engineering on the rear surface of perovskite layers and describe an innovative approach that will further boost the PSC efficiency.

About this result
This page is automatically generated and may contain information that is not correct, complete, up-to-date, or relevant to your search query. The same applies to every other page on this website. Please make sure to verify the information with EPFL's official sources.
Related concepts (32)
Perovskite solar cell
A perovskite solar cell (PSC) is a type of solar cell that includes a perovskite-structured compound, most commonly a hybrid organic–inorganic lead or tin halide-based material as the light-harvesting active layer. Perovskite materials, such as methylammonium lead halides and all-inorganic cesium lead halide, are cheap to produce and simple to manufacture. Solar-cell efficiencies of laboratory-scale devices using these materials have increased from 3.8% in 2009 to 25.
Solar cell
A solar cell, or photovoltaic cell, is an electronic device that converts the energy of light directly into electricity by the photovoltaic effect, which is a physical phenomenon. It is a form of photoelectric cell, defined as a device whose electrical characteristics, such as current, voltage, or resistance, vary when exposed to light. Individual solar cell devices are often the electrical building blocks of photovoltaic modules, known colloquially as solar panels.
Solar-cell efficiency
Solar-cell efficiency refers to the portion of energy in the form of sunlight that can be converted via photovoltaics into electricity by the solar cell. The efficiency of the solar cells used in a photovoltaic system, in combination with latitude and climate, determines the annual energy output of the system. For example, a solar panel with 20% efficiency and an area of 1 m2 will produce 200 kWh/yr at Standard Test Conditions if exposed to the Standard Test Condition solar irradiance value of 1000 W/m2 for 2.
Show more
Related publications (42)

Improving the operational stability of perovskite solar cells with cesium-doped graphene oxide interlayer

Shaik Mohammed Zakeeruddin, Aïcha Hessler-Wyser, Felix Thomas Eickemeyer, Lukas Pfeifer, Christian Michael Wolff, Rita Therisod, Mostafa Rabie Shlaly Bahr Othman, Hong Zhang, Masaud Hassan S Almalki, Anwar Qasem M Alanazi

Perovskite solar cells (PSCs) have made great advances in terms of power conversion efficiency (PCE), yet their subpar stability continues to hinder their commercialization. The interface between the perovskite layer and the charge-carrier transporting lay ...
Elsevier2024

Interface connection of functionalized carbon nanotubes for efficient and stable perovskite solar cells

Mohammad Khaja Nazeeruddin, Jianxing Xia, Ruiyuan Hu

The ionic defects of hetero-junction interfaces always attract and trap carriers via surface electrostatic forces, which are crucial for the efficiency and intrinsic stability of perovskite solar cells (PSCs). Herein, functionalized carbon nanotubes (CNTs) ...
ROYAL SOC CHEMISTRY2023

The evolution of triphenylamine hole transport materials for efficient perovskite solar cells

Mohammad Khaja Nazeeruddin

In recent years, the dramatic increase in power conversion efficiency (PCE) coupled with a decrease in the total cost of third-generation solar cells has led to a significant increase in the collaborative research efforts of academic and industrial researc ...
ROYAL SOC CHEMISTRY2022
Show more
Related MOOCs (1)
SES Swiss-Energyscope
La transition énergique suisse / Energiewende in der Schweiz

Graph Chatbot

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.