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Concept
Perovskite solar cell
Summary
A perovskite solar cell (PSC) is a type of solar cell that includes a perovskite-structured compound, most commonly a hybrid organic–inorganic lead or tin halide-based material as the light-harvesting active layer. Perovskite materials, such as methylammonium lead halides and all-inorganic cesium lead halide, are cheap to produce and simple to manufacture.
Solar-cell efficiencies of laboratory-scale devices using these materials have increased from 3.8% in 2009 to 25.7% in 2021 in single-junction architectures, and, in silicon-based tandem cells, to 29.8%, exceeding the maximum efficiency achieved in single-junction silicon solar cells. Perovskite solar cells have therefore been the fastest-advancing solar technology . With the potential of achieving even higher efficiencies and very low production costs, perovskite solar cells have become commercially attractive. Core problems and research subjects include their short- and long-term stability.
The raw materials used and the possible fabrication methods (such as various printing techniques) are both low cost. Their high absorption coefficient enables ultrathin films of around 500 nm to absorb the complete visible solar spectrum. These features combined result in the ability to create low cost, high efficiency, thin, lightweight, and flexible solar modules. Perovskite solar cells have found use in powering prototypes of low-power wireless electronics for ambient-powered Internet of things applications, and may help mitigate climate change.
Perovskite cells also possess many optoelectrical properties that benefit their use in solar cells. For example, the exciton binding energy is small. This allows electron holes and electrons to be easily separated upon the absorption of a Photon. Moreover, the long diffusion distance of the charge carrier and the high diffusivity - the rate of diffusion - allow the charge carriers to travel long distances within the perovskite solar cell, which improves the chance of it to be absorbed and converted to power.
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