Maxwell relationsMaxwell's relations are a set of equations in thermodynamics which are derivable from the symmetry of second derivatives and from the definitions of the thermodynamic potentials. These relations are named for the nineteenth-century physicist James Clerk Maxwell. symmetry of second derivatives The structure of Maxwell relations is a statement of equality among the second derivatives for continuous functions. It follows directly from the fact that the order of differentiation of an analytic function of two variables is irrelevant (Schwarz theorem).
Thermodynamic processClassical thermodynamics considers three main kinds of thermodynamic process: (1) changes in a system, (2) cycles in a system, and (3) flow processes. (1)A Thermodynamic process is a process in which the thermodynamic state of a system is changed. A change in a system is defined by a passage from an initial to a final state of thermodynamic equilibrium. In classical thermodynamics, the actual course of the process is not the primary concern, and often is ignored.
Table of thermodynamic equationsCommon thermodynamic equations and quantities in thermodynamics, using mathematical notation, are as follows: List of thermodynamic propertiesThermodynamic potentialFree entropy and Defining equation (physical chemistry) Many of the definitions below are also used in the thermodynamics of chemical reactions. Heat capacity and Thermal expansion Thermal conductivity The equations in this article are classified by subject. where kB is the Boltzmann constant, and Ω denotes the volume of macrostate in the phase space or otherwise called thermodynamic probability.
Drag coefficientIn fluid dynamics, the drag coefficient (commonly denoted as: , or ) is a dimensionless quantity that is used to quantify the drag or resistance of an object in a fluid environment, such as air or water. It is used in the drag equation in which a lower drag coefficient indicates the object will have less aerodynamic or hydrodynamic drag. The drag coefficient is always associated with a particular surface area. The drag coefficient of any object comprises the effects of the two basic contributors to fluid dynamic drag: skin friction and form drag.
Bulk modulusThe bulk modulus ( or ) of a substance is a measure of the resistance of a substance to bulk compression. It is defined as the ratio of the infinitesimal pressure increase to the resulting relative decrease of the volume. Other moduli describe the material's response (strain) to other kinds of stress: the shear modulus describes the response to shear stress, and Young's modulus describes the response to normal (lengthwise stretching) stress. For a fluid, only the bulk modulus is meaningful.
Thermodynamic systemA thermodynamic system is a body of matter and/or radiation, considered as separate from its surroundings, and studied using the laws of thermodynamics. Thermodynamic systems may be isolated, closed, or open. An isolated system exchanges no matter or energy with its surroundings, whereas a closed system does not exchange matter but may exchange heat and experience and exert forces. An open system can interact with its surroundings by exchanging both matter and energy.
Thermodynamic squareThe thermodynamic square (also known as the thermodynamic wheel, Guggenheim scheme or Born square) is a mnemonic diagram attributed to Max Born and used to help determine thermodynamic relations. Born presented the thermodynamic square in a 1929 lecture. The symmetry of thermodynamics appears in a paper by F.O. Koenig. The corners represent common conjugate variables while the sides represent thermodynamic potentials. The placement and relation among the variables serves as a key to recall the relations they constitute.
Robin boundary conditionIn mathematics, the Robin boundary condition (ˈrɒbɪn; properly ʁɔbɛ̃), or third type boundary condition, is a type of boundary condition, named after Victor Gustave Robin (1855–1897). When imposed on an ordinary or a partial differential equation, it is a specification of a linear combination of the values of a function and the values of its derivative on the boundary of the domain. Other equivalent names in use are Fourier-type condition and radiation condition.
Dirichlet boundary conditionIn the mathematical study of differential equations, the Dirichlet (or first-type) boundary condition is a type of boundary condition, named after Peter Gustav Lejeune Dirichlet (1805–1859). When imposed on an ordinary or a partial differential equation, it specifies the values that a solution needs to take along the boundary of the domain. In finite element method (FEM) analysis, essential or Dirichlet boundary condition is defined by weighted-integral form of a differential equation.
Triaxial shear testA triaxial shear test is a common method to measure the mechanical properties of many deformable solids, especially soil (e.g., sand, clay) and rock, and other granular materials or powders. There are several variations on the test. In a triaxial shear test, stress is applied to a sample of the material being tested in a way which results in stresses along one axis being different from the stresses in perpendicular directions.