Publication

Phosphorescent Neutral Iridium (III) Complexes for Organic Light-Emitting Diodes

Related publications (46)

How to blue-shift phosphorescence color of iridium(III) complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti

We achieve a 20-58 nm (610-1890 cm (1)) blue-shift of the phosphorescence maximum of iridium(III) complexes (CN)(2)Ir(NN) of 1,10-phenanthrolines (NN) by modifying the cyclometalating 2-phenylpyridine ligand (CN = ppy) with an electron-w ...

2013

Pulsed-current versus constant-voltage light-emitting electrochemical cells with trifluoromethyl-substituted cationic iridium(III) complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti, Cristina Roldán Carmona

We report on five cationic iridium(III) complexes with cyclometalating 2-(3'-trifluoromethylphenyl)pyridine and a diimine, (C boolean AND N)(2)Ir(N boolean AND N), N boolean AND N = 4,4'-R-2-2,2'-dipyridyl or 4,7-R-2-1,10-phenanthroline (R = H, Me, ...

Royal Society of Chemistry2013

Correlating the Lifetime and Fluorine Content of Iridium(III) Emitters in Green Light-Emitting Electrochemical Cells

Mohammad Khaja Nazeeruddin, Julien Edouard Frey

In light-emitting electrochemical cells, the lifetime of the device is intrinsically linked to the stability of the phosphorescent emitter. In this study, we present a series of ionic iridium(III) emitters based on cyclometalating phenylpyridine ligands wh ...

American Chemical Society2013

Bright Blue Phosphorescence from Cationic Bis-Cyclometalated Iridium(III) Isocyanide Complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti

We report new bis-cyclometalated cationic indium(III) complexes ((CN)-N-boolean AND)(2)Ir(CN-tert-Bu)(2) that have tert-butyl isocyanides as neutral auxiliary ligands and 2-phenylpyridine or 2-(4'-fluoropheny1)-R-pyridines (where R is 4-methoxy, ...

2012

On the origin of exciton formation in dye doped Alq(3) OLEDs

Libero Zuppiroli

Electrically Detected Magnetic Resonance (EDMR) was used to investigate the influence of dye doping on spin-dependent exciton formation in aluminum (III) 8-hydroxyquinoline (Alq(3)) based Organic Light Emitting Diodes (OLEDs) with different device structur ...

Springer2012

Blue Phosphorescence of Trifluoromethyl- and Trifluoromethoxy-Substituted Cationic Iridium(III) Isocyanide Complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti

We report the first comprehensive comparative synthetic, structural, electrochemical, and spectroscopic study of an extended series of fluorocarbon-modified iridium(III) complexes. We prepared seven new cationic Ir(III) complexes with tert-butyl isocyanide ...

American Chemical Society2012

Near-UV to red-emitting charged bis-cyclometallated iridium(III) complexes for light-emitting electrochemical cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti, Davide Di Censo

Herein we report a series of charged iridium complexes emitting from near-UV to red using carbene-based (NC)-C-boolean AND: ancillary ligands. Synthesis, photophysical and electrochemical properties of this series are described in detail together with X-ra ...

Royal Society of Chemistry2012

Organic Thin-Film Transistors and Circuits Fabricated by Stencil Lithography on Full-Wafer Flexible Substrates

Nenad Cvetkovic

Electronic devices based on organic semiconductors, such as field-effect transistors (OTFTs) and organic diodes have attracted significant interest as possible inexpensive and flexible alternatives to inorganic devices. Despite considerable improvement in ...

EPFL2011

Scanning Tunneling Luminescence of Pentacene Nanocrystals

Alexander Kabakchiev

Organic semiconductors are promising materials for future electronic and electroluminescence applications. A detailed understanding of organic layers and nano-sized crystals down to single molecules can address fundamental questions of contacting organic s ...

EPFL2010

Magnetic field effects on the conductivity of organic bipolar and unipolar devices at room temperature

Frank Nüesch, Libero Zuppiroli

Magnetic field effects on the conductivity of different types of organic devices: undoped and dye doped aluminium (III) 8-hydroxyquinoline (Alq3)-based organic light emitting diodes (OLEDs), electrononly Alq3-based diodes, and a hole-only N,N'-diphenyl-N,N ...

Elsevier2010

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