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Publication
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Gold-catalyzed domino processes constitute a useful alternative to C-H functionalization for the synthesis of functionalized (hetero)arenes. Herein, we report computational studies on the gold-catalyzed cyclization alkynylation of keto-allenes with ethynylbenziodoxole (EBX) reagents, which identified a gold(I) picolinate complex as the active catalyst, giving the first mechanistic insights into this transformation.
Wendy Lee Queen, Daniel Teav Sun, Shuliang Yang, Jun Li, Li Peng, Olga Syzgantseva
Margaux Nathalie Dominique Larcher