Tris-heteroleptic Iridium Complexes Based on Cyclometalated Ligands with Different Cores
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The three-dimensional (3D) structures of proteins and peptides in vivo largely determine their biological functions. In vitro these native structures and their heterogeneity reflect a subtle balance between noncovalent intramolecular interactions and those ...
The photophysical properties of two hybrid multichromophoric systems consisting of an oligophenylethynyl (OPE) scaffold decorated by 10 red or blue naphthalene diimides (NDIs) have been investigated using femtosecond spectroscopy. Ultrafast charge separati ...
The optical properties of small noble metal clusters have been studied by absorption and fluorescence for sizes between 1 and 10 atoms. The experimental technique consists in depositing size-selected clusters in a neon matrix and analyzing with a spectrome ...
Langmuir-Blodgett (LB) films containing alternating layers of the metallosurfactants bis(4,4'-tridecyl-2,2'-bipyridine)-(4,4'-dicarboxy-2,2'-bipyridine) ruthenium(II)-bis(chloride) (1) and bis[2-(2,4-difluorophenyl)pyridine](4,4'-dinonadecyl-2,2'-bipyridin ...
This thesis presents an experimental study of the energy and time-resolved optical response of chemically prepared CdSe nanoparticles with different sizes, shapes (dots, rods, and tetrapods), and lattice structures (wurtzite and zinc blende). The first par ...
The enantiomerically pure pinene-bipyridine-based receptor, (-) or (+) L-, diastereoselectively self-assembles in dry acetonitrile in the presence of Ln(III) ions (Ln = La, Pr, Nd, Sm, Eu, Gd, and Tb) to give a C-3-symmetrical, pyramidal architecture with ...
UV-Vis absorption spectra of one-electron reduction products and (MLCT)-M-3 excited states of [(ReCl)-Cl-I(CO)(3)-(N, N)] (N, N = 2,2'-bipyridine, bpy; 1,10-phenanthroline, phen) have been measured by low-temperature spectroelectrochemistry and UV-Vis tran ...
We performed fully first principles quantum mechanical calculations of the ground and excited state geometries and harmonic vibrational frequencies of two prototype cationic Ir(III) complexes showing high emission quantum efficiencies. Thanks to recent the ...
Non-polar solvation dynamics has been investigated using steady-state absorption and emission spectroscopy of the NO A(2)Sigma(+)(3ssigma) Rydberg state in fluid Ar over a wide range of densities spanning the supercritical regime. Equilibrium molecular dyn ...
A porphyrin ‘‘Mille-Feuilles” photo-electrode is fabricated layer-by-layer by deposition of anionic [zinc meso-tetrakis(p-sulfonato phenyl) porphyrin]4- (ZnTPPS4−) and positively charged polypeptides on a 11-mercaptoundecanoic acid-modified gold electrode ...