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The current interest in functionalized calixarenes with phosphorylated pendant arms resides in their coordination ability towards f elements and capability towards actinide/rare earth separation. Uranyl cation forms 1: 1 and 1: 2 (M : L) complexes with a t ...
The electrochemical behavior of a promising hydrogen/bromine redox flow battery is investigated for grid-scale energy-storage application with some of the best redox-flow-battery performance results to date, including a peak power of 1.4 W/cm(2) and a 91% ...
The limited fossil fuel resources and the increasing levels of greenhouse gases in the atmosphere are the driving forces in the research of alternative ways of energy production and storage. The use of solar energy is expected to grow as our society claims ...
Molecular hydrogen is a promising candidate to replace fossil fuels as the energy carrier. Hydrogen does not exist in its molecular form on earth and must therefore be generated, starting from hydrogen-rich compounds. Water would be a renewable resource fo ...
U(iv) promotes the disproportionation of otherwise stable uranyl(v) Schiff base complexes affording U(iv)-U(v) oxo clusters with new geometries and the first example of a U(iv)⋯UO 2 + cation-cation interaction. ...
The electronic structure of various complexes of pentavalent uranyl species, namely UO2 +, is described, using DFT methods, with the aim of understanding how the structure of the ligands may influence the localisation of the unpaired 5f electron of uranium ...
This thesis is devoted to the study of oxygen reduction reaction catalysed by porphyrins at the interface between two immiscible electrolyte solutions (ITIES). Electrochemical and spectrophotometric techniques are introduced to these interfaces in order to ...
The supramolecular assembly of Ru-bipyridine complex, coded Z-907Na, with single-walled carbon nanotube (SWNT) exhibits unique redox behavior, which is applicable for the nanotube wiring of LiFePO4 (olivine). Cyclic voltammograms of thin films of Z-907Na/S ...
This paper presents a robust electrochemical detection system composed of microfabricated electrodes and a potentiostat circuit developed for quantitative detection of biomolecules by cyclic voltammetry (CV) measurements. Compared to electrochemical cells ...
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Scanning electrochemical microscopy (SECM) has developed into an excellent and versatile technique to image heterogeneous chemical reactivities on a surface. Therefore SECM applications cover a wide range of different fields such as biology and forensic sc ...
