Spin states (d electrons)Spin states when describing transition metal coordination complexes refers to the potential spin configurations of the central metal's d electrons. For several oxidation states, metals can adopt high-spin and low-spin configurations. The ambiguity only applies to first row metals, because second- and third-row metals are invariably low-spin. These configurations can be understood through the two major models used to describe coordination complexes; crystal field theory and ligand field theory (a more advanced version based on molecular orbital theory).
Sigma modelIn physics, a sigma model is a field theory that describes the field as a point particle confined to move on a fixed manifold. This manifold can be taken to be any Riemannian manifold, although it is most commonly taken to be either a Lie group or a symmetric space. The model may or may not be quantized. An example of the non-quantized version is the Skyrme model; it cannot be quantized due to non-linearities of power greater than 4. In general, sigma models admit (classical) topological soliton solutions, for example, the Skyrmion for the Skyrme model.
String theoryIn physics, string theory is a theoretical framework in which the point-like particles of particle physics are replaced by one-dimensional objects called strings. String theory describes how these strings propagate through space and interact with each other. On distance scales larger than the string scale, a string looks just like an ordinary particle, with its mass, charge, and other properties determined by the vibrational state of the string.
Asymptotic safety in quantum gravityAsymptotic safety (sometimes also referred to as nonperturbative renormalizability) is a concept in quantum field theory which aims at finding a consistent and predictive quantum theory of the gravitational field. Its key ingredient is a nontrivial fixed point of the theory's renormalization group flow which controls the behavior of the coupling constants in the ultraviolet (UV) regime and renders physical quantities safe from divergences.
Scalar field theoryIn theoretical physics, scalar field theory can refer to a relativistically invariant classical or quantum theory of scalar fields. A scalar field is invariant under any Lorentz transformation. The only fundamental scalar quantum field that has been observed in nature is the Higgs field. However, scalar quantum fields feature in the effective field theory descriptions of many physical phenomena. An example is the pion, which is actually a pseudoscalar.
Central chargeIn theoretical physics, a central charge is an operator Z that commutes with all the other symmetry operators. The adjective "central" refers to the center of the symmetry group—the subgroup of elements that commute with all other elements of the original group—often embedded within a Lie algebra. In some cases, such as two-dimensional conformal field theory, a central charge may also commute with all of the other operators, including operators that are not symmetry generators.
Conformal field theoryA conformal field theory (CFT) is a quantum field theory that is invariant under conformal transformations. In two dimensions, there is an infinite-dimensional algebra of local conformal transformations, and conformal field theories can sometimes be exactly solved or classified. Conformal field theory has important applications to condensed matter physics, statistical mechanics, quantum statistical mechanics, and string theory. Statistical and condensed matter systems are indeed often conformally invariant at their thermodynamic or quantum critical points.
Binary relationIn mathematics, a binary relation associates elements of one set, called the domain, with elements of another set, called the codomain. A binary relation over sets X and Y is a new set of ordered pairs (x, y) consisting of elements x in X and y in Y. It is a generalization of the more widely understood idea of a unary function. It encodes the common concept of relation: an element x is related to an element y, if and only if the pair (x, y) belongs to the set of ordered pairs that defines the binary relation.
String cosmologyString cosmology is a relatively new field that tries to apply equations of string theory to solve the questions of early cosmology. A related area of study is brane cosmology. This approach can be dated back to a paper by Gabriele Veneziano that shows how an inflationary cosmological model can be obtained from string theory, thus opening the door to a description of pre-Big Bang scenarios. The idea is related to a property of the bosonic string in a curve background, better known as nonlinear sigma model.
Siegel modular formIn mathematics, Siegel modular forms are a major type of automorphic form. These generalize conventional elliptic modular forms which are closely related to elliptic curves. The complex manifolds constructed in the theory of Siegel modular forms are Siegel modular varieties, which are basic models for what a moduli space for abelian varieties (with some extra level structure) should be and are constructed as quotients of the Siegel upper half-space rather than the upper half-plane by discrete groups.
