Interfacial engineering for competitive Dye-Sensitized Solar Cells production
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This paper describes the preparation and the characterization of a photovoltaic cell based on the sensitization of a wide band gap p-type semiconductor (NiO) with a phosphorus porphyrin. A photophysical study with femtosecond transient absorption spectrosc ...
The effect of electronic and nuclear factors on the dynamics of dye-to-semiconductor electron transfer was studied employing RuII(terpy)(NCS)3 sensitizers grafted onto transparent films made of titanium dioxide nanoparticles. Various approaches were strive ...
Photoinduced electron transfer from the valence band of nanocryst. NiO, a p-type semiconductor, to an excited bound dye, Coumarin 343, and the subsequent recombination have been measured by femtosecond transient absorbance spectroscopy probing with white l ...
Systems comprising a dense TiO2 film electrode, a ruthenium polypyridine dye and a PEDOT-PSS (poly(3,4-ethylenedioxythiophene)-poly(4-styrenesulfonate)) film were prepd. The heterojunctions have photovoltaic properties, with the dye absorbing the light, th ...
Hexanethiolate monolayer-protected gold nanoclusters (MPCs) were used as redox quenchers at the polarizable water/1,2-dichloroethane (DCE) interface. Photocurrent responses originating from the heterogeneous quenching of photoexcited water soluble porphyri ...
Various characteristics of dye-sensitized nanostructured TiO2 solar cells, such as electron transport and electron lifetime, were studied in detail using monochromatic illumination conditions. The electron transport was found to be a thermally activated pr ...
The charge transport properties of the dye-sensitized solar cells consisting of Ru(dcbpyH2)2(NCS)2-sensitized nanostructured TiO2 with either redox electrolyte or CuSCN as hole conductor were compared. The electron transport time and the electron charge in ...
Nanocryst. TiO2 films, surface modified with Al3+, were manufd. by depositing a TiO2 suspension contg. small amts. of Al nitrate or Al chloride onto conducting glass substrates, followed by drying, compression, and finally heating to 530°. Electrodes prepd ...
Due to their high efficiencies and their potentially low production costs, dye-sensitized solar cells (DSSC) have attracted much attention during the last few years. The technology is based on a layer made of mesoscopic TiO2 film which significantly increa ...
The main features of the characteristic impedance spectra of dye-sensitized solar cells are described in a wide range of potential conditions: from open to short circuit. An equivalent circuit model was proposed to describe the parameters of electron trans ...