Phase and microstructure selection in peritectic alloys under high G-V ratio
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Phase equilibria in the CaO-Al2O3-Fe2O3-SO3 system have been studied, mainly at 1325 degrees C. In particular the solid solution compositions of ye'elimite Ca-4(Al6O12)SO4 and brownmillerite (C-2(A,F)) phases have been analysed and used to estimate the com ...
The enthalpies of formation of the intermetallic compounds in the Ge-Ni binary system have been determined by calorimetric measurement and first-principles calculations. Based on the results obtained and information available in the literature, the phase d ...
We use in situ observations by variable temperature transmission electron microscopy on Ga drops at the tips of GaAs nanowires to investigate the phase behavior of nanoscale Ga. Experiments on pure Ga drops are compared with drops containing well-defined l ...
Directional solidification experiments on hypoperitectic Cu-Sn alloys have been performed at very low velocity in a high thermal gradient to ensure planar front growth of both phases. The diameter of the sample has been reduced to 500 mu m to strongly redu ...
Tungsten alloys are candidate materials for DEMO divertor applications because of their high melting point and low sputtering yield. We explore, using ab initio methods, the phase stability trend of W-Ta and W-V alloys. The available experimental phase dia ...
Seven alloys of the ternary Au-Cu-Pt system, containing 75 or 76.5 wt.% Au with 0-15 wt.% Pt and heat-treated to a fully ordered condition, are examined using in-situ synchrotron radiation to determine transformation temperatures and phases formed, and to ...
Tungsten alloys are candidate materials for DEMO divertor applications because of their high melting point and low sputtering yield. We explore, using ab initio methods, the phase stability trend of W-Ta and W-V alloys. The available experimental phase dia ...
Porosity is one of the major defects in castings because it reduces the mechanical properties of a cast piece [1]. Porosity formation results from the effect of two concomitant mechanisms, namely solidification shrinkage and segregation/precipitation of ga ...
This work is motivated by an industrial interest in gaining a better understanding of the phase transformations that govern the mechanical properties of 18-carat gold alloys commonly used in jewelry applications and luxury watchmaking. These alloys fall in ...
In order to better understand the microstructure that forms during laser welding of an 18 carat gold and an austenitic stainless steel, solidification of the Au-Fe binary analog has been studied using thermal analysis and interrupted Bridgman experiments. ...